SnO2/α-MoO3 core-shell nanobelts and their extraordinarily high reversible capacity as lithium-ion battery anodes

被引:182
作者
Xue, Xin-Yu [1 ]
Chen, Zhao-Hui [1 ]
Xing, Li-Li [1 ]
Yuan, Shuang [1 ]
Chen, Yu-Jin [2 ]
机构
[1] Northeastern Univ, Coll Sci, Shenyang, Peoples R China
[2] Harbin Engn Univ, Coll Sci, Harbin, Peoples R China
基金
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词
PERFORMANCE; ELECTRODES; STORAGE; NANOPARTICLES; NANOWIRES; INSERTION; OXIDE;
D O I
10.1039/c1cc00076d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Extraordinarily high reversible capacity of lithium-ion battery anodes is realized from SnO2/alpha-MoO3 core-shell nanobelts. The reversible capacity is much higher than traditional theoretical results. Such behavior is attributed to alpha-MoO3 that makes extra Li2O reversibly convert to Li+.
引用
收藏
页码:5205 / 5207
页数:3
相关论文
共 33 条
[1]   On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries [J].
Aurbach, D ;
Markovsky, B ;
Weissman, I ;
Levi, E ;
Ein-Eli, Y .
ELECTROCHIMICA ACTA, 1999, 45 (1-2) :67-86
[2]   Remote control of living cells [J].
Chen, Christopher S. .
NATURE NANOTECHNOLOGY, 2008, 3 (01) :13-14
[3]   SnO2 Nanoparticles with Controlled Carbon Nanocoating as High-Capacity Anode Materials for Lithium-Ion Batteries [J].
Chen, Jun Song ;
Cheah, Yan Ling ;
Chen, Yuan Ting ;
Jayaprakash, N. ;
Madhavi, Srinivasan ;
Yang, Yan Hui ;
Lou, Xiong Wen .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (47) :20504-20508
[4]   Crystalline-Amorphous Core-Shell Silicon Nanowires for High Capacity and High Current Battery Electrodes [J].
Cui, Li-Feng ;
Ruffo, Riccardo ;
Chan, Candace K. ;
Peng, Hailin ;
Cui, Yi .
NANO LETTERS, 2009, 9 (01) :491-495
[5]   Porous Co3O4 nanotubes derived from Co4(CO)12 clusters on carbon nanotube templates:: A highly efficient material for Li-battery applications [J].
Du, Ning ;
Zhang, Hui ;
Chen, Bindi ;
Wu, Jianbo ;
Ma, Xiangyang ;
Liu, Zhihong ;
Zhang, Yiqiang ;
Yang, Deren ;
Huang, Xiaohua ;
Tu, Jiangping .
ADVANCED MATERIALS, 2007, 19 (24) :4505-+
[6]   Electrochemical storage of energy in carbon nanotubes and nanostructured carbons [J].
Frackowiak, E ;
Béguin, F .
CARBON, 2002, 40 (10) :1775-1787
[7]   The role of carbonate solvents on lithium intercalation into graphite [J].
Gnanaraj, J. S. ;
Thompson, R. W. ;
DiCarlo, J. F. ;
Abraham, K. M. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (03) :A185-A191
[8]   Simple synthesis of hollow tin dioxide microspheres and their application to lithium-ion battery anodes [J].
Han, SJ ;
Jang, BC ;
Kim, T ;
Oh, SM ;
Hyeon, T .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (11) :1845-1850
[9]   Carbon-coated MoO3 nanobelts as anode materials for lithium-ion batteries [J].
Hassan, M. F. ;
Guo, Z. P. ;
Chen, Z. ;
Liu, H. K. .
JOURNAL OF POWER SOURCES, 2010, 195 (08) :2372-2376
[10]   Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].
Idota, Y ;
Kubota, T ;
Matsufuji, A ;
Maekawa, Y ;
Miyasaka, T .
SCIENCE, 1997, 276 (5317) :1395-1397