Mesoporous TiO2-B Microspheres with Superior Rate Performance for Lithium Ion Batteries

被引:354
作者
Liu, Hansan [1 ]
Bi, Zhonghe [1 ]
Sun, Xiao-Guang [1 ]
Unocic, Raymond R. [2 ]
Paranthaman, M. Parans [1 ]
Dai, Sheng [1 ]
Brown, Gilbert M. [1 ]
机构
[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
[2] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA
关键词
TIO2(B); NANOTUBES; ANATASE; NANOSTRUCTURES; INTERCALATION; INSERTION;
D O I
10.1002/adma.201100599
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mesoporous TiO2-B microspheres with a favorable material architecture are designed and synthesized for highpower lithium ion batteries. This material, which combines the advantages of fast lithium transport with a pseudocapacitive mechanism, adequate electrode-electrolyte contact, and compact particle packing in the electrode layer, shows superior high-rate charge discharge capability and longtime cyclability for lithium ion batteries.
引用
收藏
页码:3450 / +
页数:6
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