Direct formation of an organonitrogen compound from a molybdenum nitrido species

被引:34
作者
Henderickx, H [1 ]
Kwakkenbos, G [1 ]
Peters, A [1 ]
van der Spoel, J [1 ]
de Vries, K [1 ]
机构
[1] DSM Res & Patents, NL-6160 MD Geleen, Netherlands
关键词
D O I
10.1039/b305774g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The molybdenum nitrido complex (NMo)-N-15[N(R)Ar](3) (where R = C(CD3)(2)CH3, Ar = 3,5-C6H3Me2) reacted with the anhydride of trifluoroacetic acid at room temperature to afford the correspondent organonitrogen compound in almost quantitative yield without the necessity of using additional reagents to achieve the C-N coupling.
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收藏
页码:2050 / 2051
页数:2
相关论文
共 26 条
[1]  
[Anonymous], 1998, SHELXTL V5 1
[2]   A low-spin d5 iron imide:: Nitrene capture by low-coordinate iron(I) provides the 4-coordinate Fe(III) complex [PhB(CH2PPh2)3]FeN-p-tolyl [J].
Brown, SD ;
Betley, TA ;
Peters, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (02) :322-323
[3]   N-2 CLEAVAGE BY 3-COORDINATE GROUP-6 COMPLEXES - W(III) COMPLEXES WOULD-BE BETTER THAN MO(III) COMPLEXES [J].
CUI, Q ;
MUSAEV, DG ;
SVENSSON, M ;
SIEBER, S ;
MOROKUMA, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (49) :12366-12367
[4]   Nitride formation by thermolysis of a kinetically stable niobium dinitrogen complex [J].
Fryzuk, MD ;
Kozak, CM ;
Bowdridge, MR ;
Patrick, BO ;
Rettig, SJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (28) :8389-8397
[5]  
Fryzuk MD, 2002, ANGEW CHEM INT EDIT, V41, P3709, DOI 10.1002/1521-3773(20021004)41:19<3709::AID-ANIE3709>3.0.CO
[6]  
2-U
[7]  
Fürstner A, 2001, CHEM-EUR J, V7, P5299, DOI 10.1002/1521-3765(20011217)7:24<5299::AID-CHEM5299>3.0.CO
[8]  
2-X
[9]   Synthesis of tungsten (1-pyridinio)imido complexes: Facile N-N bond cleavage to form pyridine from coordinated dinitrogen [J].
Ishii, Y ;
Tokunaga, S ;
Seino, H ;
Hidai, M .
INORGANIC CHEMISTRY, 1996, 35 (18) :5118-5119
[10]  
Jennings J. R., 1991, CATALYTIC AMMONIA SY