A zinc hydroxide complex of relevance to 5-aminolevulinate dehydratase:: The synthesis, structure and reactivity of the tris(2-mercapto-1-phenylimidazolyl)hydroborato complex [TmPh]ZnOH

被引:40
作者
Bridgewater, BM [1 ]
Parkin, G [1 ]
机构
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
基金
美国国家卫生研究院;
关键词
D O I
10.1016/S1387-7003(00)00218-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The tris(2-mercapto-1-phenylimidazolyl)hydroborato ligand, [Tm-Ph], has been used to prepare [Tm-Ph]ZnOH, the first structurally characterized terminal zinc hydroxide complex of a tridentate sulfur donor ligand; as such. [Tm-Ph]ZnOH represents a good structural model for the zinc enzyme 5-aminolevulinate dehydratase(ALAD). (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:126 / 129
页数:4
相关论文
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