Evidence of dimer formation in neat liquid 1,3,5-trifluorobenzene

被引：16

作者：

Cabaco, MI

Danten, Y

Besnard, M

Guissani, Y

Guillot, B

机构：

[1] UNIV BORDEAUX 1,SPECT MOL & CRISTALLINE LAB,CNRS URA 124,F-33405 TALENCE,FRANCE

[2] UNIV PARIS 06,PHYS THEOR LIQUIDES LAB,CNRS URA 765,F-75252 PARIS,FRANCE

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 262卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(96)01049-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

1,3,5-Trifluorobenzene neat liquid has been studied in comparison with benzene and perfluorinated benzene using neutron diffraction experiments and molecular dynamics simulation. These investigations reveal that the short-range local order is markedly different in 1,3,5-trifluorobenzene liquid, and involves 'dimers', in which the molecules have a parallel stacked configuration, and an average intermolecular distance of less than 4 Angstrom.

引用

收藏

页码：120 / 124

页数：5

相关论文

共 16 条

[1] A NEUTRON AND X-RAY-DIFFRACTION STUDY OF THE BINARY-LIQUID AROMATIC SYSTEM BENZENE-HEXAFLUOROBENZENE .2. THE MIXTURES [J].

BARTSCH, E ;

BERTAGNOLLI, H ;

CHIEUX, P .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1986, 90 (01) :34-46

[2] A NEUTRON AND X-RAY-DIFFRACTION STUDY OF THE BINARY-LIQUID AROMATIC SYSTEM BENZENE-HEXAFLUOROBENZENE .1. THE PURE COMPONENTS [J].

BARTSCH, E ;

BERTAGNOLLI, H ;

SCHULZ, G ;

CHIEUX, P .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1985, 89 (02) :147-156

[3]

BESNARD M, 1995, NATO ADV SCI INST SE, V452, P201

[4] FAR-INFRARED SPECTROSCOPY OF LIQUID BENZENE - LONG-RANGED AND SHORT RANGED DYNAMICS IN THE NEAT LIQUID AND IN SOLUTION [J].

BESNARD, M ;

DELCAMPO, N ;

YARWOOD, J ;

CATLOW, B .

JOURNAL OF MOLECULAR LIQUIDS, 1994, 62 :33-54

[5]

CABACO MI, IN PRESS

[6] INVESTIGATION OF CHARGE-TRANSFER COMPLEXES BY COMPUTER-SIMULATION .1. IODINE IN BENZENE SOLUTION [J].

DANTEN, Y ;

GUILLOT, B ;

GUISSANI, Y .

JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (05) :3782-3794

[7] EVIDENCE FOR THE BREAKDOWN OF THE POINT MULTIPOLE APPROXIMATION FROM FAR-INFRARED STUDIES ON LIQUID FLUORINATED BENZENES [J].

DELCAMPO, N ;

BESNARD, M ;

YARWOOD, J .

CHEMICAL PHYSICS, 1990, 142 (01) :91-95

[8] CENTRAL OR DISTRIBUTED MULTIPOLE MOMENTS - ELECTROSTATIC MODELS OF AROMATIC DIMERS [J].

FOWLER, PW ;

BUCKINGHAM, AD .

CHEMICAL PHYSICS LETTERS, 1991, 176 (01) :11-18

[9] THE STRUCTURE OF THE MOLECULAR LIQUIDS CARBON-MONOXIDE (CO) AND NITRIC-OXIDE (NO) AS DETERMINED BY NEUTRON-SCATTERING [J].

HOWE, MA ;

WORMALD, CJ ;

NEILSON, GW .

MOLECULAR PHYSICS, 1989, 66 (04) :847-858

[10] THEORY OF INTERMOLECULAR PAIR CORRELATIONS FOR MOLECULAR LIQUIDS - APPLICATIONS TO LIQUIDS CARBON-TETRACHLORIDE, CARBON-DISULFIDE, CARBON DISELENIDE, AND BENZENE [J].

LOWDEN, LJ ;

CHANDLER, D .

JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (12) :5228-5241