'Inverse crown ether' complexes:: extension to potassium through the synthesis of [{[(Me3Si)2N]4K2Mg2(O2)}∞], a peroxo-centred macrocycle linked into infinite chains by intermolecular K•••CH3(SiMe2) interactions

被引：57

作者：

Kennedy, AR

Mulvey, RE ^{[1
]}

Raston, CL

Roberts, BA

Rowlings, RB

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[2] Monash Univ, Dept Chem, Clayton, Vic 3168, Australia

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 04期

关键词：

D O I：

10.1039/a809681c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)(2+) octagonal ring framework surrounding a dianionic (O-2)(2-) core.

引用

页码：353 / 354

页数：2

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