Structural diversity of lithium neopentoxide compounds

被引：32

作者：

Boyle, TJ ^{[1
]}

Alam, TM ^{[1
]}

Peters, KP ^{[1
]}

Rodriguez, MA ^{[1
]}

机构：

[1] Sandia Natl Labs, Adv Mat Lab, Albuquerque, NM 87105 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 24期

关键词：

D O I：

10.1021/ic0106569

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of LiN(SiMe3)(2) with 1 equiv of HOCH2CMe3 (HONep) in toluene led to the formation of [Li(mu (3)-ONep)](8) (1). The complex adopts a novel dual-edge fused hexagon-square prismatic structure with a C-2 nu axis of rotation that relates the top and bottom eight-membered rings. Substituting the noncoordinating solvent toluene for a Lewis basic solvent (THF or py) led to the isolation of compounds of the general formula [Li(mu (3)-ONep)](4)-(solv)(3), where solv = THF (2) or py (3). The cube structures of 2 and 3 have one Li which is not solvated because of steric crowding of the ONep ligands. Multinuclear solid-state (Li-6, Li-7, and C-13) MAS and solution-state (H-1, Li-7, and C-13) NMR studies were undertaken to verify the identity of the bulk powder and to determine the solution behavior of these compounds.

引用

页码：6281 / 6286

页数：6

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