Two new bismutho(III)polytungstates, Na10[Bi2Ni2W20O70(H2O)6].26H2O and Na8[Bi2W22O70(OH)6].31H2O

被引：26

作者：

Rodewald, D ^{[1
]}

Jeannin, Y ^{[1
]}

机构：

[1] Univ Paris 06, URA CNRS 419, Chim Met Transit Lab, F-75252 Paris 05, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1998年 / 1卷 / 03期

关键词：

bismutho(III)polytungstates; crystallographic structures; polytungstates;

D O I：

10.1016/S1387-1609(99)80077-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new bismutho(III)polyrungstates Na-10[Bi2Ni2W20O70(H2O)(6)].26H(2)O (1) and Na-8 [Bi2W22O70(OH)(6)].31H(2)O (2) were prepared and studied by X-ray diffraction. They are made of two type beta-B BiW9O33 units; in each of them one W3O13 group is turned by 60 degrees. These units are connected by four octahedra. While BiW9O33 Octahedra have only one terminal oxygen atom, two of those four connecting octahedra have two terminal oxygen atoms and the two others have three facial ligands, water molecules or hydroxide anions, i.e. NiO3(H2O)(3) for (1) and WO3(OH)(3) for (2). (C) Academie des Sciences/Elsevier, Paris.

引用

页码：175 / 181

页数：7

共 18 条

[1] New strategies for the generation of large heteropolymetalate clusters: The beta-B-SbW9 fragment as a multifunctional unit [J].

Bosing, M ;

Loose, I ;

Pohlmann, H ;

Krebs, B .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (08) :1232-1237

[2] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[3] STRUCTURE OF HETEROPOLYTUNGSTATE (NH-4)17NA/NAW21SB9O-86/.14H-2O - INORGANIC CRYPTATE [J].

FISCHER, J ;

RICARD, L ;

WEISS, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (10) :3050-3052

[4] X-RAY STUDY OF (NH4)7[H2ASW18O60].16H2O - 1ST EXAMPLE OF A HETEROPOLYANION CONTAINING PROTONS AND ARSENIC(III) [J].

JEANNIN, Y ;

MARTINFRERE, J .

INORGANIC CHEMISTRY, 1979, 18 (11) :3010-3014

[5] W-183 NMR AND X-RAY STUDY OF A HETEROPOLYANION [AS2W21O69(H2O)]6- EXHIBITING A RARE SQUARE-PYRAMIDAL ENVIRONMENT FOR SOME TUNGSTEN(VI) [J].

JEANNIN, Y ;

MARTINFRERE, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (07) :1664-1667

[6]

KREBS B, 1994, SYNTHESIS STRUCTURAL, P41

[7] SYNTHESIS AND X-RAY STRUCTURE OF THE 1ST MERCURY(I)-CONTAINING POLYTUNGSTATE, [(HG2)2WO(H2O)(ASW9O33)2]10-, WITH AN ODD OPEN-SHELL STRUCTURE [J].

MARTINFRERE, J ;

JEANNIN, Y .

INORGANIC CHEMISTRY, 1984, 23 (21) :3394-3398

[8]

MICHELON M, 1971, CR ACAD SCI C CHIM, V273, P1117

[9]

MICHELON M, 1972, CR ACAD SCI C CHIM, V274, P209

[10]

MICHELON M, 1995, THESIS U P M CURIE

← 1 2 →