Novel thiosalamo ligand as a remarkably stable N2S2 salen-type chelate and synthesis of a nickel(II) complex

被引：56

作者：

Akine, S ^{[1
]}

Nabeshima, T ^{[1
]}

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 05期

关键词：

D O I：

10.1021/ic048347g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel N2S2 tetradentate chelate ligand H(2)tsalamo, which contains both thiol groups and C=N moieties, was synthesized as a remarkably stable compound. Complexation between H2tsalamo and nickel(II) acetate gave a square planar complex [Ni(tsalamo)] as dark brown crystals, whose structure was determined by X-ray crystallography. In contrast, the corresponding N2O2 ligands, salamo and 3-MeOsalamo, gave trinuclear and mononuclear complexes, respectively, in which all the nickel atoms have octahedral geometry.

引用

页码：1205 / 1207

页数：3

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