A Biologically Inspired Organometallic Fuel Cell (OMFC) That Converts Renewable Alcohols into Energy and Chemicals

被引：63

作者：

Annen, Samuel P. ^{[2
]}

Bambagioni, Valentina ^{[1
]}

Bevilacqua, Manuela ^{[1
]}

Filippi, Jonathan ^{[1
]}

Marchionni, Andrea ^{[1
]}

Oberhauser, Werner ^{[1
]}

Schoenberg, Hartmut ^{[2
]}

Vizza, Francesco ^{[1
]}

Bianchini, Claudio ^{[1
]}

Gruetzmacher, Hansjoerg ^{[2
]}

机构：

[1] Polo Sci Area CNR, Inst Chem Organometall Cpds, ICCOM CNR, I-50019 Sesto Fiorentino, Italy

[2] ETH Honggerberg, Dept Chem & Appl Biosci, CH-8093 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 40期

基金：

瑞士国家科学基金会;

关键词：

electrochemistry; energy conversion; fuel cells; renewable resources; sustainable chemistry; ANION-EXCHANGE MEMBRANE; ETHANOL OXIDATION; RHODIUM(I) AMIDES; HYDROGEN-TRANSFER; ELECTROCATALYSTS; PALLADIUM; METHANOL; WATER; PD;

D O I：

10.1002/anie.201002234

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Embedded and working: The intact deposition of a complex into carbon powder allows the construction of an organome- tallic fuel cell (OMFC) that efficiently converts alcohols into carboxylic acids. This method may provide a way for the synthesis offine chemicals from renewable resources under waste-free conditions. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7229 / 7233

页数：5

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