CNT-based electrodes with high efficiency for PEMFCs

被引:124
作者
Wang, X [1 ]
Waje, M
Yan, YS
机构
[1] Univ Calif Riverside, Dept Chem & Environm Engn, Coll Engn, Riverside, CA 92521 USA
[2] Univ Calif Riverside, Ctr Environm Res & Technol, Coll Engn, Riverside, CA 92521 USA
关键词
D O I
10.1149/1.1830397
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A highly efficient fuel cell electrode structure based on carbon nanotubes (CNTs) is demonstrated. The CNTs were grown on carbon paper by chemical vapor deposition using electrodeposited Co/Ni catalyst. Pt was subsequently deposited by spraying of Pt precursor on CNTs followed by in situ reduction in hydrogen. Cyclic voltammograms show a significant improvement in the Pt utilization in the CNT-based electrode over conventional electrode (58% vs. 34%). Higher membrane electrode assembly performance was observed for CNT-based electrode with a maximum power density of 623 mW cm(-2) at Pt loading of 0.15 mg/cm(2), 70 degrees C and 3 atm. (C) 2004 The Electrochemical Society.
引用
收藏
页码:A42 / A44
页数:3
相关论文
共 14 条
[1]  
[Anonymous], [No title captured]
[2]  
Britto PJ, 1999, ADV MATER, V11, P154, DOI 10.1002/(SICI)1521-4095(199902)11:2<154::AID-ADMA154>3.0.CO
[3]  
2-B
[4]  
Dujardin E, 1998, ADV MATER, V10, P611, DOI 10.1002/(SICI)1521-4095(199805)10:8<611::AID-ADMA611>3.0.CO
[5]  
2-8
[6]   Recent progress in performance improvement of the proton exchange membrane fuel cell (PEMFC) [J].
Gamburzev, S ;
Appleby, AJ .
JOURNAL OF POWER SOURCES, 2002, 107 (01) :5-12
[7]   Preparation and characterization of multiwalled carbon nanotube-supported platinum for cathode catalysts of direct methanol fuel cells [J].
Li, WZ ;
Liang, CH ;
Zhou, WJ ;
Qiu, JS ;
Zhou, ZH ;
Sun, GQ ;
Xin, Q .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (26) :6292-6299
[8]   Oxygen electroreduction on carbon-supported platinum catalysts.: Particle-size effect on the tolerance to methanol competition [J].
Maillard, F ;
Martin, M ;
Gloaguen, F ;
Léger, JM .
ELECTROCHIMICA ACTA, 2002, 47 (21) :3431-3440
[9]   Carbon nanofiber supported palladium catalyst for liquid-phase reactions.: An active and selective catalyst for hydrogenation of C=C bonds [J].
Pham-Huu, C ;
Keller, N ;
Charbonniere, LJ ;
Ziessle, R ;
Ledoux, MJ .
CHEMICAL COMMUNICATIONS, 2000, (19) :1871-1872
[10]   Composite electrodes made of Pt nanoparticles deposited on carbon nanotubes grown on fuel cell backings [J].
Sun, X ;
Li, R ;
Villers, D ;
Dodelet, JP ;
Désilets, S .
CHEMICAL PHYSICS LETTERS, 2003, 379 (1-2) :99-104