Carbon-nitrogen bond cleavage in pyridine ring systems mediated by organometallic thorium(IV) complexes

被引:45
作者
Pool, JA [1 ]
Scott, BL [1 ]
Kiplinger, JL [1 ]
机构
[1] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA
关键词
D O I
10.1039/b502439k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Thorium(IV) alkyl and aryl complexes of the type (C5Me5)(2)ThR2 (R = CH2Ph, Ph) have been found to mediate the facile ring-opening and dearomatization of the pyridine ring of pyridine N-oxide under ambient conditions to afford the first thorium eta(2)-(O, N)-oximate complexes.
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页码:2591 / 2593
页数:3
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