Electrospinning of thermo-regulating ultrafine fibers based on polyethylene glycol/cellulose acetate composite

被引:140
作者
Chen, Changzhong
Wang, Linge [1 ]
Huang, Yong
机构
[1] Chinese Acad Sci, Guanbzhou Inst Chem, Key Lab Cellulose & Lignocelluls, Guangzhou 510650, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
[3] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
electrospinning; phase change material; thermo-regulating fibers;
D O I
10.1016/j.polymer.2007.06.069
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Ultrafine fibers of polyethylene glycol/cellulose acetate (PEG/CA) composite in which PEG acts as a model phase change material (PCM) and CA acts as a matrix, were successfully prepared as thermo-regulating fibers via electrospinning. The morphology observation from the electrospun PEG/CA composite fibers revealed that the fibers were cylindrical and had a smooth external surface. PEG was found to be both distributed on the surface and within the core of the fibers. Differential scanning calorimeter (DSC) was used to characterize the thermal properties of the composite fibers. The results indicated that the fibers imparted balanced thermal storage and release properties for their thermo-regulating function and the thermal properties were reproducible after 100 heating-cooling cycles. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5202 / 5207
页数:6
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