Novel polymer/salt hybrid composed of comblike organoboron polymer electrolyte and boron-stabilized imido anion

被引：20

作者：

Matsumi, N ^{[1
]}

Nakashiba, M ^{[1
]}

Mizumo, T ^{[1
]}

Ohno, H ^{[1
]}

机构：

[1] Tokyo Univ Agr & Technol, Dept Biotechnol, Tokyo 1848588, Japan

来源：

MACROMOLECULES | 2005年 / 38卷 / 06期

关键词：

D O I：

10.1021/ma047469p

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of comblike organoboron polymer electrolyte bearing an boron-stabilized imido anion (BSI) unit was discussed. Hydroboration polymerization between 1,7-octadiene and the monomembrane- dimethyl sulfide complex was carried out and the obtained poly(organoboron halide) was reacted with n-hexylamine and then with poly(ethylene glycol) monomethyl ether. The polymers showed an ionic conductivity of 1.31 × 10-4-1.32 × 10-5 S/cm at 323 K. The high dissociation degree of lithium BSI salt due to pπ-pπ interaction in the boron-nitrogen bond was also elaborated.

引用

页码：2040 / 2042

页数：3

共 35 条

[1] Polyphosphazenes bearing branched and linear oligoethyleneoxy side groups as solid solvents for ionic conduction [J].

Allcock, HR ;

OConnor, SJM ;

Olmeijer, DL ;

Napierala, ME ;

Cameron, CG .

MACROMOLECULES, 1996, 29 (23) :7544-7552

[2]

BLONSKY PM, 1984, J AM CHEM SOC, V106, P6854, DOI 10.1021/ja00334a071

[3] SYNTHESIS OF POLY(ORGANOBORON HALIDE)S BY HYDROBORATION POLYMERIZATION BETWEEN DIENE AND MONOBROMOBORANE [J].

CHUJO, Y ;

TAKIZAWA, N ;

SAKURAI, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (02) :227-228

[4] HYDROBORATION POLYMERIZATION OF DICYANO COMPOUNDS .1. SYNTHESIS OF BORON-CONTAINING POLYMERS BY THE REACTION BETWEEN T-BUBH2.NME3 AND DICYANO COMPOUNDS [J].

CHUJO, Y ;

TOMITA, I ;

MURATA, N ;

MAUERMANN, H ;

SAEGUSA, T .

MACROMOLECULES, 1992, 25 (01) :27-32

[5] HYDROBORATION POLYMERIZATION .1. SYNTHESIS OF ORGANOBORON POLYMERS BY POLYADDITION BETWEEN DIENE AND MONOALKYLBORANE [J].

CHUJO, Y ;

TOMITA, I ;

HASHIGUCHI, Y ;

TANIGAWA, H ;

IHARA, E ;

SAEGUSA, T .

MACROMOLECULES, 1991, 24 (02) :345-348

[6] SYNTHESIS AND ELECTRICAL RESPONSE OF SINGLE-ION CONDUCTING NETWORK POLYMERS BASED ON SODIUM POLY(TETRAALKOXYALUMINATES) [J].

DOAN, KE ;

RATNER, MA ;

SHRIVER, DF .

CHEMISTRY OF MATERIALS, 1991, 3 (03) :418-423

[7] SYNTHESIS, PROPERTIES, AND REACTIONS OF BIS((TRIFLUOROMETHYL)SULFONYL) IMIDE, (CF3SO2)2NH [J].

FOROPOULOS, J ;

DESMARTEAU, DD .

INORGANIC CHEMISTRY, 1984, 23 (23) :3720-3723

[8] Siloxyaluminate polymers with high Li+ ion conductivity [J].

Fujinami, T ;

Tokimune, A ;

Mehta, MA ;

Shriver, DF ;

Rawsky, GC .

CHEMISTRY OF MATERIALS, 1997, 9 (10) :2236-2239

[9] Analysis of recent measurements of the viscosity of glasses [J].

Fulcher, GS .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1925, 8 (06) :339-355

[10] CATIONIC CONDUCTIVITY AND RELAXATION PROCESSES IN SOLID POLYMER ELECTROLYTES WITH LITHIUM PERFLUOROALKYL SULFONATE OR SULFONATO END-CAPPED POLY(ETHYLENE OXIDE) [J].

HAMAIDE, T ;

LEDEORE, C .

POLYMER, 1993, 34 (05) :1038-1046

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