Polyacrylonitrile single-walled carbon nanotube composite fibers

被引:311
作者
Sreekumar, TV
Liu, T
Min, BG
Guo, H
Kumar, S [1 ]
Hauge, RH
Smalley, RE
机构
[1] Georgia Inst Technol, Sch Polymer Text & Fiber Engn, Atlanta, GA 30332 USA
[2] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA
[3] Kumoh Inst Technol, Sch Adv Mat & Ssyt Engn, Kumi 730701, South Korea
关键词
D O I
10.1002/adma.200305456
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polyacrylonitrile (PAN) containing 10 wt.-% single-walled carbon nanotubes (SWNTs) exhibit a 100% improvement in tensile modulus and reduced thermal shrinkage and polymer solubility. A 40degreesC increase in glass transition temperature as compared to the control PAN fiber is also observed (see Figure). SWNT anisotropy has been observed using infrared spectroscopy.
引用
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页码:58 / +
页数:5
相关论文
共 29 条
[1]   Nanotube composite carbon fibers [J].
Andrews, R ;
Jacques, D ;
Rao, AM ;
Rantell, T ;
Derbyshire, F ;
Chen, Y ;
Chen, J ;
Haddon, RC .
APPLIED PHYSICS LETTERS, 1999, 75 (09) :1329-1331
[2]   Organic solvent dispersions of single-walled carbon nanotubes: Toward solutions of pristine nanotubes [J].
Ausman, KD ;
Piner, R ;
Lourie, O ;
Ruoff, RS ;
Korobov, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (38) :8911-8915
[3]   Dissolution of small diameter single-wall carbon nanotubes in organic solvents? [J].
Bahr, JL ;
Mickelson, ET ;
Bronikowski, MJ ;
Smalley, RE ;
Tour, JM .
CHEMICAL COMMUNICATIONS, 2001, (02) :193-194
[4]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[5]   Purification and characterization of single-wall carbon nanotubes [J].
Chiang, IW ;
Brinson, BE ;
Smalley, RE ;
Margrave, JL ;
Hauge, RH .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (06) :1157-1161
[6]  
Cullity B.D., 1978, ELEMENTS XRAY DIFFRA, V2nd, P102
[7]   Elastic constants of textured short-fiber composites [J].
Dunn, ML ;
Ledbetter, H ;
Heyliger, PR ;
Choi, CS .
JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 1996, 44 (09) :1509-+
[8]   Magnetically aligned single wall carbon nanotube films: Preferred orientation and anisotropic transport properties [J].
Fischer, JE ;
Zhou, W ;
Vavro, J ;
Llaguno, MC ;
Guthy, C ;
Haggenmueller, R ;
Casavant, MJ ;
Walters, DE ;
Smalley, RE .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (04) :2157-2163
[9]   Fibers of aligned single-walled carbon nanotubes: Polarized Raman spectroscopy [J].
Gommans, HH ;
Alldredge, JW ;
Tashiro, H ;
Park, J ;
Magnuson, J ;
Rinzler, AG .
JOURNAL OF APPLIED PHYSICS, 2000, 88 (05) :2509-2514
[10]   Surfactant-assisted processing of carbon nanotube/polymer composites [J].
Gong, XY ;
Liu, J ;
Baskaran, S ;
Voise, RD ;
Young, JS .
CHEMISTRY OF MATERIALS, 2000, 12 (04) :1049-1052