Synthesis of a first-row transition metal parent amido complex and carbon monoxide insertion into the amide N-H bond

被引：59

作者：

Fox, DJ

Bergman, RG ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Ctr New Direct Organ Synth, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 30期

关键词：

D O I：

10.1021/ja035707a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The parent amido iron complex (dmpe)2Fe(H)(NH2) (dmpe = 1,2-bis(dimethylphosphino)ethane), the first such first-row transition metal complex, has been synthesized and characterized spectroscopically and crystallographically. This complex has been found to insert carbon monoxide into the amide N-H bond (rather than the M-N bond) to give trans-(dmpe)2Fe(H)(NHCHO). The mechanism of this transformation has been studied and is believed to occur through an unusual mechanism in which CO behaves as an apparent electrophile. Copyright © 2003 American Chemical Society.

引用

收藏

页码：8984 / 8985

页数：2

相关论文

共 24 条

[1]

[Anonymous], UNPUB

[2] REACTION OF SP2 C-H BONDS IN UNACTIVATED ALKENES WITH BIS(DIPHOSPHINE) COMPLEXES OF IRON [J].

BAKER, MV ;

FIELD, LD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (23) :7433-7434

[3] FORMATION OF MOLECULAR-HYDROGEN COMPLEXES OF IRON BY THE REVERSIBLE PROTONATION OF IRON DIHYDRIDES WITH ALCOHOLS [J].

BAKER, MV ;

FIELD, LD ;

YOUNG, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (08) :546-548

[4] SYNTHESIS AND REACTIONS OF MONOMERIC LATE TRANSITION-METAL ALKOXO, ARYLOXO AND HYDROXO COMPLEXES [J].

BERGMAN, RG .

POLYHEDRON, 1995, 14 (22) :3227-3237

[5] MECHANISM OF CO INSERTION INTO METAL-OXYGEN BONDS - REACTION OF (DPPE)PT(OCH3)R (R = CH3 OR OCH3) WITH CO [J].

BRYNDZA, HE .

ORGANOMETALLICS, 1985, 4 (09) :1686-1687

[6] PREPARATION AND CHEMISTRY OF NOVEL PLATINUM(II) AMIDE COMPLEXES CONTAINING BETA-HYDROGENS [J].

BRYNDZA, HE ;

FULTZ, WC ;

TAM, W .

ORGANOMETALLICS, 1985, 4 (05) :939-940

[7] MONOMERIC METAL-HYDROXIDES, ALKOXIDES, AND AMIDES OF THE LATE TRANSITION-METALS - SYNTHESIS, REACTIONS, AND THERMOCHEMISTRY [J].

BRYNDZA, HE ;

TAM, W .

CHEMICAL REVIEWS, 1988, 88 (07) :1163-1188

[8] PHOTOCHEMICAL-REACTIONS OF [CIS-FE(H)(2)(ME(2)PCH(2)CH2(P)ME(2))(2)] WITH THIOPHENES - INSERTION INTO C-H AND C-S BONDS [J].

BUYS, IE ;

FIELD, LD ;

HAMBLEY, TW ;

MCQUEEN, AED .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (05) :557-558

[9]

Collman J.P., 1987, PRINCIPLES APPL ORGA

[10] Insertion of CO2, CS2, and COS into iron(II)-hydride bonds [J].

Field, LD ;

Lawrenz, ET ;

Shaw, WJ ;

Turner, P .

INORGANIC CHEMISTRY, 2000, 39 (25) :5632-5638