Solvothermal synthesis of [Cr10(μ-O2CMe)10(μ-OR)20] 'chromic wheels' with antiferromagnetic (R = Et) and ferromagnetic (R = Me) Cr(III)•••Cr(III) interactions

被引：75

作者：

McInnes, EJL

Anson, C

Powell, AK

Thomson, AJ

Poussereau, S

Sessoli, R

机构：

[1] Univ E Anglia, Sch Chem Sci, Norwich NR4 7TJ, Norfolk, England

[2] Univ Florence, Dipartimento Chim, I-50144 Florence, Italy

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 01期

关键词：

D O I：

10.1039/b007773i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two decanuclear cyclic Cr(iii) complexes have been synthesised in high yield by solvothermal techniques: magnetic susceptibility studies reveal ferromagnetic Cr . . . Cr exchange in one, and antiferromagnetic Cr . . . Cr exchange in the other.

引用

页码：89 / 90

页数：2

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