Quantum linear magnetic chains: structure and magnetic behavior of (2-methylpyrazine)copper(II) nitrate

被引：33

作者：

Amaral, S

Jensen, WE

Lande, CP

Turnbull, MM

Woodward, FM

机构：

[1] Clark Univ, Dept Phys, Worcester, MA 01610 USA

[2] Clark Univ, Carlson Sch Chem & Biochem, Worcester, MA 01610 USA

来源：

POLYHEDRON | 2001年 / 20卷 / 11-14期

关键词：

antiferromagnet; linear chains; copper(II); 2-methylpyrazine;

D O I：

10.1016/S0277-5387(01)00612-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The X-ray structure, susceptibility and magnetization of (2-methylpyrazine)copper(II) nitrate are reported. The compound crystallizes in the space group Pmna as a coordination polymer of Cu(II) ions bridged by 2-methylpyrazine. The resulting chains are magnetically well isolated and the susceptibility of the compound is well modeled as a one-dimensional Heisenberg antiferromagnet with 2J = 9.5(1) K. High-field magnetization studies to 30 T confirm the value of the exchange constant. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1317 / 1322

页数：6

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