Water condensation in hydrophobic nanopores

被引：146

作者：

Desbiens, N

Demachy, I

Fuchs, AH ^{[1
]}

Kirsch-Rodeschini, H

Soulard, M

Patarin, J

机构：

[1] CNRS, Chim Phys Lab, F-91405 Orsay, France

[2] Univ Paris 11, F-91405 Orsay, France

[3] Ecole Natl Super Chim, Lab Mat Porosite Controlee, CNRS, F-68093 Mulhouse, France

[4] Univ Haute Alsace, F-68093 Mulhouse, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 33期

关键词：

adsorption; molecular modeling; phase transitions; water; zeolites;

D O I：

10.1002/anie.200501250

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Simple but effective: The intrusion/extrusion cycle of a nonwetting fluid in a Hydrophobic solid can be described by simple models and simulation methods found useful for studying gas adsorption in nanoporous materials. The water confined to hydrophobic spaces of nanoscopic dimensions in the zeolite silicalite-1 is shown to be a strongly depleted and highly inhomogeneous fluid (see picture). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：5310 / 5313

页数：4

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