Green methodology for the preparation of disulfide

被引:17
作者
Attri, Pankaj [1 ]
Gupta, Shweta [1 ]
Kumar, Rupesh [1 ]
机构
[1] Univ Delhi, Dept Chem, Delhi 110007, India
关键词
thiols; disulfides; oxidation; ascorbic acid; water; MOLECULAR-INTERACTIONS; SILICA-GEL; THIOLS; OXIDATION; EFFICIENT; DERIVATIVES; OXIDANT; AGENT; ACID;
D O I
10.1080/17518253.2011.578080
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
A very simple, green method for the efficient oxidation of thiols to disulfides catalyzed by ascorbic acid was found to be practical, inexpensive, and reusable and has a simple work-up procedure. This oxidation is suitable for a variety of thiols at room temperature and proceeds cleanly in short reaction time and with high yields.
引用
收藏
页码:33 / 42
页数:10
相关论文
共 38 条
[1]
Oxidation of thiols to disulfides with molecular bromine on hydrated silica gel support [J].
Ali, MH ;
McDermott, M .
TETRAHEDRON LETTERS, 2002, 43 (35) :6271-6273
[2]
Simple ammonium ionic liquid catalyses the 1,5-benzodiazepine derivatives under mild conditions [J].
Attri, Pankaj ;
Pal, Mohinder .
GREEN CHEMISTRY LETTERS AND REVIEWS, 2010, 3 (03) :249-256
[3]
Temperature Effect on the Molecular Interactions between Ammonium Ionic Liquids and N,N-Dimethylformamide [J].
Attri, Pankaj ;
Venkatesu, Pannuru ;
Kumar, Anil .
JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (42) :13415-13425
[4]
Measurements and Molecular Interactions for N,N-Dimethylformamide with Ionic Liquid Mixed Solvents [J].
Attri, Pankaj ;
Reddy, P. Madhusudan ;
Venkatesu, P. ;
Kumar, Anil ;
Hofman, T. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (18) :6126-6133
[5]
THE ORGANOSULFUR CHEMISTRY OF THE GENUS ALLIUM - IMPLICATIONS FOR THE ORGANIC-CHEMISTRY OF SULFUR [J].
BLOCK, E .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1992, 31 (09) :1135-1178
[6]
CAPOZZI G, 1974, CHEM THIOL GROUP 2
[7]
Cremlyn RJ., 1996, An introduction to organosulfur chemistry
[8]
DHAR DN, 1984, INDIAN J CHEM B, V23, P974
[9]
F-19 NMR-STUDY OF THE REACTION OF PARA-FLUOROBENZENETHIOL AND DISULFIDE WITH PERIODATE AND OTHER SELECTED OXIDIZING-AGENTS [J].
EVANS, BJ ;
DOI, JT ;
MUSKER, WK .
JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (08) :2337-2344
[10]
OXIDATION OF THIOLS TO THEIR DISULFIDES WITH BIS [TRINITRATOCERIUM (IV)] CHROMATE [CE(NO3)3]2 CRO4 AND PYRIDINUM CHLOROCHROMATE [J].
FIROUZABADI, H ;
IRANPOOR, N ;
PARHAM, H ;
SARDARIAN, A ;
TOOFAN, J .
SYNTHETIC COMMUNICATIONS, 1984, 14 (08) :717-723