Adamantyl-endcapped polyynes

被引：24

作者：

Chalifoux, Wesley A.

Ferguson, Michael J. ^{[2
]}

McDonald, Robert ^{[2
]}

Melin, Frederic ^{[3
]}

Echegoyen, Luis ^{[4
]}

Tykwinski, Rik R. ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

[2] Univ Alberta, Dept Chem, Xray Crystallog Lab, Edmonton, AB T6G 2G2, Canada

[3] Univ Strasbourg, Inst Chim, F-67070 Strasbourg, France

[4] Univ Texas El Paso, Dept Chem, El Paso, TX 79968 USA

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2012年 / 25卷 / 01期

基金：

加拿大自然科学与工程研究理事会; 美国国家科学基金会;

关键词：

adamantane; carbyne; conjugated oligomers; Fritsch-Buttenberg-Wiechell rearrangement; polyynes; NONLINEAR-OPTICAL PROPERTIES; HIGHER CONJUGATED POLYYNES; CARBON ALLOTROPE CARBYNE; BOND-LENGTH ALTERNATION; MIT UROTROPIN-STRUKTUR; AR-CC-CCH; OXIDATIVE COUPLINGS; STRUCTURAL-ANALYSIS; CRYSTAL-STRUCTURES; PROTECTIVE METHOD;

D O I：

10.1002/poc.1874

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学];

摘要：

Polyynes spanning from a diyne to a dodecayne with adamantyl endgroups have been synthesized using the FritschButtenbergWiechell rearrangement as a key step to construct the acetylenic framework. Molecular properties as a function of polyyne length have been analyzed by UVVis spectroscopy, cyclic voltammetry, differential scanning calorimetry, and X-ray crystallography. Copyright (C) 2011 John Wiley & Sons, Ltd.

引用

页码：69 / 76

页数：8

共 55 条

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