The effects of promoters in carbon monoxide hydrogenation on cobalt foil model catalysts

被引:21
作者
Lahtinen, J
Somorjai, GA
机构
[1] Univ Calif Berkeley, Div Sci Mat, Lawrence Berkeley Lab, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
D O I
10.1016/S1381-1169(97)00216-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carbon monoxide hydrogenation has been studied on polycrystalline cobalt foils, using a combination of UHV studies and atmospheric pressure reactions at 525 and 575 K and the effects of different promoters (K and Mg) have been investigated. The selectivity towards methane was decreased due to both promoters. The main effect with potassium was,however, the suppression of carbon deposition at higher reaction temperatures. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:255 / 260
页数:6
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