Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex

被引：37

作者：

Chatwin, SL

Diggle, RA

Jazzar, RFR

Macgregor, SA

Mahon, MF

Whittlesey, MK ^{[1
]}

机构：

[1] Heriot Watt Univ, Sch Engn & Phys Sci, Edinburgh EH14 4AS, Midlothian, Scotland

[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 24期

关键词：

D O I：

10.1021/ic030241i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Addition of 1 atm of H2S to [Ru(IMeS)(2)(CO)(EtOH)H-2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMeS)(2)(CO)(H2S)H-2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMeS)(2)(CO)(SH)(2)] 3. Preliminary studies show that 3 reacts with both H-2 and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized.

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页码：7695 / 7697

页数：3

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