A pure bismuth a site polar perovskite synthesized at ambient pressure

被引：35

作者：

Bridges, Craig A.

Allix, Mathieu

Suchomel, Matthew R.

Kuang, Xiaojun

Sterianou, Iasmi

Sinclair, Derek C.

Rosseinsky, Matthew J. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

[2] Univ Sheffield, Dept Elect Mat, Sheffield S1 3JD, S Yorkshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 46期

基金：

英国工程与自然科学研究理事会;

关键词：

bismuth; ferroelectric materials; neutron diffraction; perovskite phases; polarity;

D O I：

10.1002/anie.200703146

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) Getting the lead out: The bonding preferences of three octahedral-site cations permit the accommodation of the small, low-symmetry Bi3+ cation on the twelve-coordinate A site of the perovskite structure, affording a lead-free ferroelectric material (see picture). The graph shows the temperature dependence of the relative permittivity (Ο, left axis) and the dielectric loss (Δ, right axis). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：8785 / 8789

页数：5

相关论文

共 21 条

[1] Structure determination of ferromagnetic perovskite BiMnO3 [J].

Atou, T ;

Chiba, H ;

Ohoyama, K ;

Yamaguchi, Y ;

Syono, Y .

JOURNAL OF SOLID STATE CHEMISTRY, 1999, 145 (02) :639-642

[2] Theoretical prediction of new high-performance lead-free piezoelectrics [J].

Baettig, P ;

Schelle, CF ;

LeSar, R ;

Waghmare, UV ;

Spaldin, NA .

CHEMISTRY OF MATERIALS, 2005, 17 (06) :1376-1380

[3] Origin of the monoclinic-to-monoclinic phase transition and evidence for the centrosymmetric crystal structure of BiMnO3 [J].

Belik, Alexei A. ;

Iikubo, Satoshi ;

Yokosawa, Tadahiro ;

Kodama, Katsuaki ;

Igawa, Naoki ;

Shamoto, Shinichi ;

Azuma, Masaki ;

Takano, Mikio ;

Kimoto, Koji ;

Matsui, Yoshio ;

Takayama-Muromachi, Eiji .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (04) :971-977

[4] A neutron diffraction investigation into the rhombohedral phases of the perovskite series PbZr1-xTixO3 [J].

Corker, DL ;

Glazer, AM ;

Whatmore, RW ;

Stallard, A ;

Fauth, F .

JOURNAL OF PHYSICS-CONDENSED MATTER, 1998, 10 (28) :6251-6269

[5] New high temperature morphotropic phase boundary piezoelectrics based on Bi(Me)O3-PbTiO3 ceramics [J].

Eitel, RE ;

Randall, CA ;

Shrout, TR ;

Rehrig, PW ;

Hackenberger, W ;

Park, SE .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2001, 40 (10) :5999-6002

[6]

FILIPEV VS, 1960, KRISTALLOGRAFIYA, V5, P958

[7] Oxide chemistry and local structure of PbZrxTi1-xO3 studied by density-functional theory supercell calculations -: art. no. 144118 [J].

Grinberg, I ;

Cooper, VR ;

Rappe, AM .

PHYSICAL REVIEW B, 2004, 69 (14) :144118-1

[8] Ferroelectric ceramics: History and technology [J].

Haertling, GH .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1999, 82 (04) :797-818

[9] A polar oxide with a large magnetization synthesized at ambient pressure [J].

Hughes, H ;

Allix, MMB ;

Bridges, CA ;

Claridge, JB ;

Kuang, XJ ;

Niu, HJ ;

Taylor, S ;

Song, WH ;

Rosseinsky, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (40) :13790-13791

[10] High pressure synthesis, crystal structure and physical properties of a new Ni(II) perovskite BiNiO3 [J].

Ishiwata, S ;

Azuma, M ;

Takano, M ;

Nishibori, E ;

Takata, M ;

Sakata, M ;

Kato, K .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (12) :3733-3737