Synthesis of a C3-symmetric ferrocenylphosphine and its application to the Suzuki reaction of aryl chlorides

被引：42

作者：

Pickett, TE ^{[1
]}

Richards, CJ ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(01)00568-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(S-p,S-p,S-p)-Tris(2-methyl ferrocenyl)phosphine 1 was synthesised in 62% yield from (S)-2-ferrocenyl-4-(1-methylethyl)oxazoline. In combination with Pd(2)dba(3) this novel C-3-symmetric ligand generates a catalyst for the Suzuki reaction of aryl chloride substrates, these reactions proceed readily at 60 degreesC in dioxane. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：3767 / 3769

页数：3

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