Enhanced absorption induced by a metallic nanoshell

被引:74
作者
Baer, R [1 ]
Neuhauser, D
Weiss, S
机构
[1] Hebrew Univ Jerusalem, Dept Phys Chem, IL-91904 Jerusalem, Israel
[2] Hebrew Univ Jerusalem, Lise Meitner Ctr Quantum Chem, IL-91904 Jerusalem, Israel
[3] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
关键词
D O I
10.1021/nl034902k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanoshells have been previously shown to have tunable absorption frequencies that are dependent on the ratio of their inner and outer radii. Inspired by this, we ask: can a nanoshell increase the absorption of a small core system embedded within it? A theoretical model is constructed to answer this question. A core, composed of a "jellium" ball of the density of gold is embedded within a jellium nanoshell of nanometric diameter. The shell plasmon frequency is tuned to the core absorption line. A calculation based the time-dependent density functional theory was performed showing a 10 fold increase in core excitation yield.
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页码:85 / 88
页数:4
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