Scanning probe studies of porphyrin assemblies and their supramolecular manipulation at a solid-liquid interface

被引:71
作者
Elemans, JAAW [1 ]
Lensen, MC [1 ]
Gerritsen, JW [1 ]
van Kempen, H [1 ]
Speller, S [1 ]
Nolte, RJM [1 ]
Rowan, AE [1 ]
机构
[1] Univ Nijmegen, NSRIM Lab, NL-6525 ED Nijmegen, Netherlands
关键词
D O I
10.1002/adma.200305602
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dynamic self-assembly and metal-ligand coordination processes of porphyrin hexamers on a solid-liquid interface have been visualized with scanning tunneling microscopy. The organization of these hexamers into stable and highly organized arrays of edge-on or face-on oriented molecules can be controlled by the addition of different ditopic axial ligands (see Figure).
引用
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页码:2070 / +
页数:5
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