Poly[[diaquacadmium(II)]-μ3-(1-carboxybenzene-3,5dicarboxylato)]

被引:5
作者
Skakle, JMS
Foreman, MRS
Plater, MJ
Griffin, C
机构
[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland
[2] Univ Aberdeen, Sch Phys, Aberdeen AB24 3UE, Scotland
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词
D O I
10.1107/S160053680100188X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The crystal structure of the title complex, poly[[diaquacadmium(II)]-mu (3) -(1-carboxybenzene-3,5-dicarboxylato-O-1:O-3,O-3':O-5,O-5')], [Cd(C9H4O6)(H2O)(2)](n), features two-dimensional polymeric network layers which are hydrogen-bonded to one another. The Cd atom is coordinated by seven O atoms, two of which belong to water molecules arranged trans to each other, above and below the layers. Each polymeric layer is tiled with (Cd)(3)(C9O6)(3) rings formed by alternating Cd atoms and (C9O6) ligands. The layers are parallel to the (1) over bar 01 crystal plane and the neighbouring layers are separated by 3.2508 (2) Angstrom.
引用
收藏
页码:M85 / M87
页数:3
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