Structural studies of solid methane at high pressures

被引:37
作者
Nakahata, I [1 ]
Matsui, N [1 ]
Akahama, Y [1 ]
Kawamura, H [1 ]
机构
[1] Himeji Inst Technol, Fac Sci, Kamigori, Hyogo 6781297, Japan
关键词
D O I
10.1016/S0009-2614(99)00092-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High-pressure X-ray powder diffraction measurements for solid methane were performed at pressures up to 13 GPa. The diffraction pattern at 7.0 GPa is assigned to a rhombohedral lattice with lattice constants of a = 8.643(1) Angstrom and alpha = 89.40(2)degrees and with a unit cell that contains 21 molecules. The bulk modulus of the rhombohedral phase is estimated to be 7.9(3) GPa. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:359 / 362
页数:4
相关论文
共 14 条
[1]   WEAK INFRARED BANDS IN SOLID CH4-II [J].
BACIOCCO, G ;
CALVANI, P ;
CUNSOLO, S .
JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (04) :1913-1916
[2]   FAR-INFRARED SPECTRUM OF SOLID METHANE - PHASE-II [J].
BARAN, BW ;
MEDINA, FD .
CHEMICAL PHYSICS LETTERS, 1986, 129 (02) :125-129
[3]   FAR-INFRARED SPECTRUM OF SOLID METHANE - PHASE-III AND PHASE-IV [J].
BARAN, BW ;
MEDINA, FD .
CHEMICAL PHYSICS LETTERS, 1991, 176 (06) :509-513
[4]   High-pressure infrared study of solid methane: Phase diagram up to 30 GPa [J].
Bini, R ;
Pratesi, G .
PHYSICAL REVIEW B, 1997, 55 (22) :14800-14809
[5]   HIGH-PRESSURE CRYSTAL PHASES OF SOLID CH4 PROBED BY FOURIER-TRANSFORM INFRARED-SPECTROSCOPY [J].
BINI, R ;
ULIVI, L ;
JODL, HJ ;
SALVI, PR .
JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (04) :1353-1360
[6]   THE NEAR-INFRARED SPECTRUM OF SOLID CH4 [J].
CALVANI, P ;
CUNSOLO, S ;
LUPI, S ;
NUCARA, A .
JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (10) :7372-7379
[7]   THE STRUCTURE OF SOLID CARBON TETRAFLUORIDE [J].
FITCH, AN ;
COCKCROFT, JK .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1993, 203 :29-39
[8]   STRUCTURE AND COMPRESSION OF CRYSTALLINE METHANE AT HIGH-PRESSURE AND ROOM-TEMPERATURE [J].
HAZEN, RM ;
MAO, HK ;
FINGER, LW ;
BELL, PM .
APPLIED PHYSICS LETTERS, 1980, 37 (03) :288-289
[9]   OPTICAL STUDIES OF METHANE UNDER HIGH-PRESSURE [J].
HEBERT, P ;
POLIAN, A ;
LOUBEYRE, P ;
LETOULLEC, R .
PHYSICAL REVIEW B, 1987, 36 (17) :9196-9201
[10]   RAMAN-SPECTRUM OF PHASE-III OF SOLID CH4 IN THE LATTICE AND INTRA-MOLECULAR REGIONS [J].
MEDINA, FD ;
DANIELS, WB .
JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (06) :2688-2694