Factors influencing the rate of Fe2O3 conversion reaction

被引：76

作者：

Jiao, Feng ^{[1
]}

Bao, Jianli ^{[1
]}

Bruce, Peter G. ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem & EastChem, St Andrews KY16 9ST, Fife, Scotland

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2007年 / 10卷 / 12期

关键词：

D O I：

10.1149/1.2783268

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The conversion reaction process shows a higher capacity than graphite (1000 mAh g(-1) compared with 370 mAh g(-1)) but suffers from a number of problems, including low rate capability. Using mesoporous, nanoparticulate, and bulk Fe2O3, we examine the factors influencing the rate of the Fe2O3 conversion electrode, demonstrating that electron transport to and within the particles is rate limiting. A composite electrode based on Fe2O3 can store 700 mAh g(-1) at 3000 mA g(-1) (6 mAh cm(-2) at 26 mA cm(-2)). (c) 2007 The Electrochemical Society.

引用

页码：A264 / A266

页数：3

共 16 条

[1] Nanostructured materials for advanced energy conversion and storage devices [J].

Aricò, AS ;

Bruce, P ;

Scrosati, B ;

Tarascon, JM ;

Van Schalkwijk, W .

NATURE MATERIALS, 2005, 4 (05) :366-377

[2] Fully reversible homogeneous and heterogeneous Li storage in RuO2 with high capacity [J].

Balaya, P ;

Li, H ;

Kienle, L ;

Maier, J .

ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (08) :621-625

[3]

Débart A, 2001, J ELECTROCHEM SOC, V148, pA1266, DOI 10.1149/1.1409971

[4] Electrochemical properties of nano-sized Fe2O3-loaded carbon as a lithium battery anode [J].

Hang, Bui Thi ;

Watanabe, Izumi ;

Doi, Takayuki ;

Okada, Shigeto ;

Yamaki, Jun-Ichi .

JOURNAL OF POWER SOURCES, 2006, 161 (02) :1281-1287

[5] Fabrication of nano/micro hierarchical Fe2O3/Ni micrometer-wire structure and characteristics for high rate Li rechargeable battery [J].

Hosono, Eiji ;

Fujihara, Shinobu ;

Honma, Itaru ;

Ichihara, Masaki ;

Zhou, Haoshen .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (07) :A1273-A1278

[6] Ordered mesoporous Fe2O3 with crystalline walls [J].

Jiao, F ;

Harrison, A ;

Jumas, JC ;

Chadwick, AV ;

Kockelmann, W ;

Bruce, PG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (16) :5468-5474

[7] Synthesis of ordered mesoporous Fe3O4 and γ-Fe2O3 with crystalline walls using post-template reduction/oxidation [J].

Jiao, Feng ;

Jumas, Jean-Claude ;

Womes, Manfred ;

Chadwick, Alan V. ;

Harrison, Andrew ;

Bruce, Peter G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (39) :12905-12909

[8] Combined XRD, EXAFS, and Mossbauer studies of the reduction by lithium of α-Fe2O3 with various particle sizes [J].

Larcher, D ;

Bonnin, D ;

Cortes, R ;

Rivals, I ;

Personnaz, L ;

Tarascon, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (12) :A1643-A1650

[9] Effect of particle size on lithium intercalation into α-Fe2O3 [J].

Larcher, D ;

Masquelier, C ;

Bonnin, D ;

Chabre, Y ;

Masson, V ;

Leriche, JB ;

Tarascon, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (01) :A133-A139

[10] The electrochemical reduction of Co3O4 in a lithium cell [J].

Larcher, D ;

Sudant, G ;

Leriche, JB ;

Chabre, Y ;

Tarascon, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (03) :A234-A241

← 1 2 →