Syntheses and crystal structures of the heterobimetallic eicosanuclear clusters [Et(4)N](4)[M(8)Cu(12)S(28)O(4)]center dot DMF (M=Mo,W)

被引:7
作者
Huang, Q [1 ]
Wu, XT [1 ]
Sheng, TL [1 ]
Wang, QM [1 ]
机构
[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,STATE KEY LAB STRUCT CHEM,FUJIAN 350002,PEOPLES R CHINA
关键词
D O I
10.1016/0277-5387(96)00060-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The title clusters were produced by reaction of (NH4)(2)MS(4) and (NH4)(2)MO(2)S(2) with Cu-I cations in DMF. The structures consist of M atoms in an approximate cubane array and Cu atoms almost lying along the edges of this cubane between the M atoms (M = Mo, W). Copyright (C) 1996 Elsevier Science Ltd.
引用
收藏
页码:3405 / 3410
页数:6
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