A new route to cyclen, cyclam and homocyclen.

被引：54

作者：

Hervé, G

Bernard, H

Le Bris, N

Yaouanc, JJ

Handel, H

Toupet, L

机构：

[1] Univ Bretagne Occidentale, F-29285 Brest, France

[2] CNRS, F-29285 Brest, France

[3] Univ Rennes 1, F-35042 Rennes, France

[4] CNRS, GMCM, F-35042 Rennes, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 38期

关键词：

bis-aminals; butanedione; cyclization; tetraazamacrocycles;

D O I：

10.1016/S0040-4039(98)01497-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyclen, cyclam and homocyclen have been synthesized from the corresponding butanedione-protected linear tetramines. The cyclization step is followed by a facile deprotection of the rigidifying moiety. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：6861 / 6864

页数：4

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