Chloride ion binding capacity of aluminoferrites

被引:96
作者
Csizmadia, J
Balázs, G [1 ]
Tamás, FD
机构
[1] Tech Univ Budapest, Dept Bldg Mat & Engn Geol, Budapest, Hungary
[2] Univ Veszprem, Dept Silicat & Mat Engn, H-8201 Veszprem, Hungary
基金
匈牙利科学研究基金会;
关键词
calcium aluminoferrite; chloride; thermal analysis; X-ray diffraction;
D O I
10.1016/S0008-8846(01)00458-6
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The hydration of aluminoferrites (C(4)AF, C(6)AF(2) and C(6)A(2)F) and their mixture with gypsum (up to 10/5 ratio) was investigated as well as their chloride binding capacity (after immersion in 10% NaCl solution) by thermal tests (DTG and TGA) and X-ray diffraction (XRD). Hydration products of these aluminoferrites are similar to that of C(3)A, but amorphous AH(3) and/or FH3 are formed, and transformation of metastable (hexagonal hydrates) to the stable (hydrogarnet) phase is slower. Iron content of aluminoferrites determines the rate of hydration reactions: hydration rate increases in the order C(6)A(2)F > C(4)AF > C(6)AF(2) In the case of C(4)AF + gypsum mixtures, monosulfate was found prior to the total exhaustion of gypsum. After salt treatment, iron-containing Friedel's salt or Kuzel's salt was found. Characteristics of DTG peaks are described and interpreted. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:577 / 588
页数:12
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