β-fluorinated porphyrins and related compounds:: An overview

被引：25

作者：

Leroy, Jacques ^{[1
]}

Bondon, Arnaud ^{[2
]}

机构：

[1] Ecole Normale Super, Dept Chim, CNRS, UMR 8640, F-75231 Paris 05, France

[2] Univ Rennes 1, RMN ILP, CNRS, UMR 6026,IFR 140,PRISM, F-35043 Rennes, France

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 2008卷 / 03期

关键词：

fluorinated ligands; porphyrinoids; nitrogen heterocycles; synthetic methods;

D O I：

10.1002/ejoc.200700734

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Apart from a few examples, beta-(poly)fluorinated and beta-(poly)-perfluoroalkylated porphyrins were practically unknown until recently. In particular, beta-octafluoro-meso-tetraarylporphyrins remained elusive ligands owing to the lack of any convenient access. The aim of this microreview is to highlight recent progress in the synthesis and characterization of beta-fluoroporphyrins and beta-(perfluoroalkyl)porphyrins, two new classes of so-called electron-deficient porphyrins. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).

引用

页码：417 / 433

页数：17

共 134 条

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