High activity TiO2 photocatalysts prepared by a modified sol-gel method:: characterization and their photocatalytic activity for the degradation of XRG and X-GL

被引：51

作者：

Zhu, JF

Zhang, JL

Chen, F

Iino, K

Anpo, M

机构：

[1] E China Univ Sci & Technol, Lab Adv Mat, Shanghai 200237, Peoples R China

[2] E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

[3] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Osaka 5998531, Japan

来源：

TOPICS IN CATALYSIS | 2005年 / 35卷 / 3-4期

关键词：

photocatalytic activity; esterification reaction; modified sol-gel method; TiO2 (B);

D O I：

10.1007/s11244-005-3833-1

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A simple method for preparing high photocatalytic activity TiO2 has been developed by controlled the hydrolysis of titanium butoxide with water generated "in situ" using an esterification reaction between the acetic acid and ethanol. The photocatalytic activity of the samples prepared was higher than that of the reference Degussa P25 TiO2 for the liquid phase photocatatlytic degradation of active yellow XRG dye and cationic golden X-GL dye.

引用

页码：261 / 268

页数：8

共 34 条

[1] The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation
Anpo, M
Takeuchi, M
[J]. JOURNAL OF CATALYSIS, 2003, 216 (1-2) : 505 - 516
[2] STRUCTURE-ANALYSIS OF NA2TI9O19 BY 1-MV HIGH-RESOLUTION ELECTRON-MICROSCOPY
BANDO, Y
WATANABE, M
SEKIKAWA, Y
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (JUL): : 1541 - 1545
[3] A STRUCTURAL INVESTIGATION OF TITANIUM-DIOXIDE PHOTOCATALYSTS
BICKLEY, RI
GONZALEZCARRENO, T
LEES, JS
PALMISANO, L
TILLEY, RJD
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1991, 92 (01) : 178 - 190
[4] Photocatalytic behaviour of sulphated TiO2 for phenol degradation
Colón, G
Hidalgo, MC
Navío, JA
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 45 (01) : 39 - 50
[5] Cullity BD, 1978, ELEMENTS XRAY DIFFRA
[6] HYDROLYSIS OF TITANIUM ALKOXIDES - MODIFICATION OF THE MOLECULAR PRECURSOR BY ACETIC-ACID
DOEUFF, S
HENRY, M
SANCHEZ, C
LIVAGE, J
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1987, 89 (1-2) : 206 - 216
[7] FENG SH, 1998, SCIENCE, V281, P802
[8] HETEROGENEOUS PHOTOCATALYSIS
FOX, MA
DULAY, MT
[J]. CHEMICAL REVIEWS, 1993, 93 (01) : 341 - 357
[9] Fujishima A., 2000, J PHOTOCH PHOTOBIO C, V1, P1, DOI DOI 10.1016/S1389-5567(00)00002-2
[10] INTERACTIONS OF PRECIPITATED HEMATITE WITH PREFORMED COLLOIDAL TITANIA DISPERSIONS
GHERARDI, P
MATIJEVIC, E
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1986, 109 (01) : 57 - 68

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