The Y2BaCuO5 oxide as green pigment in ceramics

被引：20

作者：

Fernandez, F ^{[1
]}

Colon, C

Duran, A

Barajas, R

d'Ors, A

Becerril, M

Llopis, J

Paje, SE

Saez-Puche, R

Julian, I

机构：

[1] EUITI UPM, Dept Ind & Polimeros Q, E-28012 Madrid, Spain

[2] Ayuntamiento Madrid, Escuela Madrilena Ceram Moncloa, E-28008 Madrid, Spain

[3] Univ Complutense Madrid, Fac Ciencias Fis, Dept Fis Mat, E-28040 Madrid, Spain

[4] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Inorgan, E-28040 Madrid, Spain

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1998年 / 275卷

关键词：

pigments; Y2BaCuO5; green phases; ceramics;

D O I：

10.1016/S0925-8388(98)00427-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fine particles of green yttrium-barium-copper-oxide pigments Y2BaCuO5 have been prepared using two different synthesis methods. The process of combustion of mixed nitrates and urea needs a maximal temperature of 900 degrees C and provides samples formed by aggregates of homogeneous small particles with a size of about 0.3 mu m. However, the ceramic method requires 1050 degrees C as synthesis temperature, and yields rather higher particle sizes. Even after grinding, these samples are formed by heterogeneous particles with mean sizes of about 3 mu m. Diffuse reflectance spectra reveal that the samples obtained using the former method present a higher brilliancy, so they have been selected to be tested as green pigment in ceramics with good results. (C) 1998 Elsevier Science S.A.

引用

页码：750 / 753

页数：4

共 11 条

[1]

BERNARD C, 1982, J SOLID STATE CHEM, V43, P73

[2]

Carvajal J. R., 1990, SAT M POWD DIFFR 15, P127

[3]

Eppler RA., 1986, ULLMANNS ENCY IND A, VA5, P545

[4]

MACAUDIERE P, 1994, Patent No. 01560

[5]

MACAUDIERE P, 1995, Patent No. 680930

[6]

MAESTRO P, 1985, Patent No. 0203838

[7] Influence of calcination temperature on lattice parameters and particle size of R(2)CuO(4) compounds (R=Gd, Nd) prepared by a sol-gel [J].

Mahia, J ;

Vieiro, A ;

Mira, J ;

Rivas, J ;

LopezQuintela, MA ;

Oseroff, SB .

JOURNAL OF SOLID STATE CHEMISTRY, 1996, 122 (01) :25-30

[8] EVIDENCE OF ANTIFERROMAGNETIC ORDER IN THE GREEN PHASES DYBACUO5, YBACUO5, YBBACUO5 [J].

SALINASSANCHEZ, A ;

SAEZPUCHE, R ;

ALARIOFRANCO, MA .

JOURNAL OF SOLID STATE CHEMISTRY, 1990, 89 (02) :361-365

[9]

SANCHEZ AS, 1992, DOCTOR ACCESITH

[10]

SANCHEZ AS, 1992, J SOLID STATE CHEM, V100, P443

← 1 2 →