Supramolecular inclusion complexes of fullerenes using cyclotriveratrylene derivatives with aromatic pendants

被引：68

作者：

Matsubara, H ^{[1
]}

Hasegawa, A

Shiwaku, K

Asano, K

Uno, M

Takahashi, S

Yamamoto, K

机构：

[1] Univ Osaka Prefecture, Coll Integrated Arts & Sci, Dept Chem, Sakai, Osaka 5998531, Japan

[2] Osaka Univ, Inst Sci & Ind Res, Ibaraki, Osaka 5670047, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 09期

关键词：

D O I：

10.1246/cl.1998.923

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CTV derivatives with aromatic pendants were synthesized and their inclusion abilities for C-60 and C-70 were examined by UV spectroscopy. CTV derivative with three N-methylpyrrole pendants showed the highest association constant for C-60 (48000 dm(3)mol(-1) in benzene). The structure of inclusion complex for C-60 with CTV derivative which has six benzoyl pendants has been determined by single-crystal X-ray diffraction.

引用

收藏

页码：923 / 924

页数：2

相关论文

共 17 条

[1] C-60 EMBEDDED IN GAMMA-CYCLODEXTRIN - A WATER-SOLUBLE FULLERENE [J].

ANDERSSON, T ;

NILSSON, K ;

SUNDAHL, M ;

WESTMAN, G ;

WENNERSTROM, O .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (08) :604-606

[2] A GAS-PHASE CONTAINER FOR C-60 - A GAMMA-CYCLODEXTRIN DIMER [J].

ANDERSSON, T ;

WESTMAN, G ;

STENHAGEN, G ;

SUNDAHL, M ;

WENNERSTROM, O .

TETRAHEDRON LETTERS, 1995, 36 (04) :597-600

[3] Molecular design of calixarene-based host molecules for inclusion of C-60 in solution [J].

Araki, K ;

Akao, K ;

Ikeda, A ;

Suzuki, T ;

Shinkai, S .

TETRAHEDRON LETTERS, 1996, 37 (01) :73-76

[4] PURIFICATION OF C-60 AND C-70 BY SELECTIVE COMPLEXATION WITH CALIXARENES [J].

ATWOOD, JL ;

KOUTSANTONIS, GA ;

RASTON, CL .

NATURE, 1994, 368 (6468) :229-231

[5]

ATWOOD JL, 1996, J CHEM SOC CHEM COMM, P1449

[6]

BARBOUR LJ, 1997, J CHEM SOC CHEM COMM, P1439

[7] OPTICAL-ACTIVITY DUE TO ISOTOPIC-SUBSTITUTION - SYNTHESIS, STEREOCHEMISTRY, AND CIRCULAR-DICHROISM OF (+)-[2,7,12-H-2(3)]CYCLOTRIBENZYLENE AND (-)-[2,7,12-H-2(3)]CYCLOTRIBENZYLENE [J].

CANCEILL, J ;

COLLET, A ;

GOTTARELLI, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (20) :5997-6003

[8] New supramolecular complex of C-60 based on calix[5]arene - Its structure in the crystal and in solution [J].

Haino, T ;

Yanase, M ;

Fukazawa, Y .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (03) :259-260

[9] Solution complexes formed from C-60 and calixarenes. On the importance of the preorganized structure for cooperative interactions [J].

Ikeda, A ;

Yoshimura, M ;

Shinkai, S .

TETRAHEDRON LETTERS, 1997, 38 (12) :2107-2110

[10] STRUCTURE OF CYCLOTRIVERATRYLENE (10,15-DIHYDRO-2,3,7,8,12,13-HEXAMETHOXY-5H-TRIBENZO[A,D,G]CYCLONONENE) AND RELATED COMPOUNDS [J].

LINDSEY, AS .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (MAR) :1685-&