New quinone diimine complex of zinc with pH-dependent emission in the visible region

被引：41

作者：

Dollberg, CL ^{[1
]}

Turro, C ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 11期

关键词：

D O I：

10.1021/ic0012524

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new emissive complex, Zn(bqdi)(H2O2)(2)(2+), was synthesized, and its photophysical properties were investigated. Zn(bqdi)(H2O)(2)(2+) emits strongly in the visible region at pH = 8.0, but the intensity decreases by a factor of 8 at pH = 3.0. The ability of the complex to "turn on" its emission as a function of pH may prove useful in switching or sensing applications.

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页码：2484 / +

页数：3

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