The design of second-order nonlinear optical chromophores exhibiting blue-shifted absorption and large nonlinearities: the role of the combined conjugation bridge
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作者:
Luo, JD
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机构:Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
Luo, JD
Hua, JL
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机构:Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
Hua, JL
Qin, JG
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Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R ChinaWuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
Qin, JG
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Cheng, JQ
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机构:Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
Cheng, JQ
Shen, YC
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机构:Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
Shen, YC
Lu, ZH
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机构:Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
Lu, ZH
Wang, P
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机构:Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
Wang, P
Ye, C
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机构:Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
Ye, C
机构:
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
[2] Southeast Univ, Natl Lab Mol & Biomol Elect, Nanjing 210096, Peoples R China
[3] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Two new extended chromophoric systems, in which a 4-aminoazobenzene moiety is linked to a cyclo-bridged hexatriene electron withdrawing group, have been synthesized, and show large optical nonlinearities and unexpected blue-shifted absorption in comparison with shorter chain analogues.