The design of second-order nonlinear optical chromophores exhibiting blue-shifted absorption and large nonlinearities: the role of the combined conjugation bridge

被引:151
作者
Luo, JD
Hua, JL
Qin, JG [1 ]
Cheng, JQ
Shen, YC
Lu, ZH
Wang, P
Ye, C
机构
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
[2] Southeast Univ, Natl Lab Mol & Biomol Elect, Nanjing 210096, Peoples R China
[3] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
关键词
D O I
10.1039/b007653h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two new extended chromophoric systems, in which a 4-aminoazobenzene moiety is linked to a cyclo-bridged hexatriene electron withdrawing group, have been synthesized, and show large optical nonlinearities and unexpected blue-shifted absorption in comparison with shorter chain analogues.
引用
收藏
页码:171 / 172
页数:2
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