A fluidized bed photoreactor exploiting a supported photocatalyst with adsorption pre-concentration capacity

被引：15

作者：

Vaisman, E

Kabir, MF

Kantzas, A

Langford, CH

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Univ Calgary, Dept Chem & Petr Engn, Calgary, AB T2N 1N4, Canada

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 2005年 / 35卷 / 7-8期

关键词：

adsorbent; catalyst support; fluidized bed; photocatalyst; photocatalytic; reactor; titanium dioxide; zeolite;

D O I：

10.1007/s10800-005-1389-1

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Laboratory and small pilot scale fluidized bed photoreactors are described that utilize an integrated photocatalyst adsorbent (IPCA) mounted on porous silica beads as support protecting against IPCA attrition. The active material is Degussa P-25 TiO2 bound to a Silicalite I zeolite adsorbent. Operating conditions for fluidization that achieves uniform illumination of photoactive particles are determined. Axial and multi-lamp configurations are compared. The small pilot reactor is calibrated against the laboratory reactor. Sub-stoichiometric acceleration of phenol oxidation by H2O2 was observed.

引用

页码：675 / 681

页数：7

共 16 条

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[Anonymous], 1993, ADV PHOTOCHEM

[2]

[Anonymous], PHOTOCHEMISTRY

[3]

Augugliaro V, 1997, WS PHOTOSCI PHOTOENG, V3, P169

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