New porous crystals of Cu(I) complexes with Schiff-base-containing

被引：58

作者：

Drabent, K ^{[1
]}

Bialonska, A ^{[1
]}

Ciunik, Z ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 02期

关键词：

metal complexes; nitrogen heterocycles; Schiff bases; N ligands; copper;

D O I：

10.1016/j.inoche.2003.11.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new route of syntheses, crystal structure and properties of two new copper(I) complexes, (CuL21)(2)(BF4)(2).0.5THF (1) and (CuL22)(2)(BF4)(2) (2) where L-1=N-[(E)-(4-chlorophenyl)methylidene]-4H-1,2,4-triazol-4-amine and L-2=N-[(E)-(3,5-dimethoxyphenyl)methylidene]-4H-1,2,4-triazol-4-amine are described. The planar dimeric molecules of 1 and 2 have a great ability toward building the porous, structures of the crystals. The size of formed channels depends on the type of substituents on phenyl group of ligands. (C) 2003 Elsevier B.V. All rights reserved.

引用

收藏

页码：224 / 227

页数：4

相关论文

共 14 条

[1] SYNTHESIS, X-RAY STRUCTURE, AND CATALYTIC PROPERTIES OF THE UNPRECEDENTED TETRANUCLEAR COPPER(I) SPECIES [CU(DPPZ)]4 (HDPPZ = 3,5-DIPHENYLPYRAZOLE) [J].

ARDIZZOIA, GA ;

CENINI, S ;

LAMONICA, G ;

MASCIOCCHI, N ;

MORET, M .

INORGANIC CHEMISTRY, 1994, 33 (07) :1458-1463

[2]

Ciunik Z, 2001, POL J CHEM, V75, P1475

[3]

Drabent K, 2003, EUR J INORG CHEM, P1548

[4]

Filinchuk YE, 1999, POL J CHEM, V73, P1283

[5] Mononuclear, oligonuclear and polynuclear metal coordination compounds with 1,2,4-triazole derivatives as ligands [J].

Haasnoot, JG .

COORDINATION CHEMISTRY REVIEWS, 2000, 200 :131-185

[6] STUDIES ON THE FORMATION OF 4-AMINOTRIAZOLE DERIVATIVES FROM ACYL HYDRAZIDES [J].

HERBST, RM ;

GARRISON, JA .

JOURNAL OF ORGANIC CHEMISTRY, 1953, 18 (07) :872-877

[7]

Ion A, 2002, EUR J INORG CHEM, P1357

[8] Different oxidation states of copper(I, I/II, II) thiocyanate complexes containing 1,2,4-triazole as a bridging ligand:: Syntheses, crystal structures, and magnetic properties of 2-D polymer CuI(admtrz)SCN, linear trinuclear [CuI2CuII(admtrz)6(SCN)2](ClO4)2, and triangular trinuclear [CuII3(admtrz)4(SCN)3(μ3-OH)(H2O)](ClO4)2•H2O(admtrz = 4-amino-3,5-dimethyl-1,2,4-triazole) [J].

Liu, JC ;

Guo, GC ;

Huang, JS ;

You, XZ .

INORGANIC CHEMISTRY, 2003, 42 (01) :235-243

[9] STRUCTURAL STUDIES OF COPPER(I) BINDING BY HYDROTRIS(1-PYRAZOLYL)BORATE AND HYDROTRIS(3,5-DIMETHYL-1-PYRAZOLYL)BORATE IN SOLID-STATE AND IN SOLUTION [J].

MEALLI, C ;

ARCUS, CS ;

WILKINSON, JL ;

MARKS, TJ ;

IBERS, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (03) :711-718

[10] A new one-dimensional copper(I) halide lattice:: (paraquat)Cu4Cl6 [J].

Place, H ;

Scott, B ;

Willett, RD .

INORGANICA CHIMICA ACTA, 2001, 319 (1-2) :43-48