Highly porous electrodes from novel corn grains-based activated carbons for electrical double layer capacitors

被引：260

作者：

Balathanigaimani, M. S. ^{[2
]}

Shim, Wang-Geun ^{[2
]}

Lee, Min-Joo ^{[2
]}

Kim, Chan ^{[1
]}

Lee, Jae-Wook ^{[3
]}

Moon, Hee ^{[2
]}

机构：

[1] AMOMEDI Co Ltd, Gimpo, South Korea

[2] Chonnam Natl Univ, Fac Appl Chem Engn, Ctr Funct Nano Fine Chem, Kwangju, South Korea

[3] Chosun Univ, Dept Chem & Biochem Engn, Kwangju, South Korea

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2008年 / 10卷 / 06期

关键词：

corn grains; activated carbon; surface functional groups; adsorption energy distribution; electrical double layer capacitor;

D O I：

10.1016/j.elecom.2008.04.003

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In this study, novel corn grains-based activated carbons (CG-ACs) were prepared and their use as electrodes in the electrical double layer capacitor (EDLC) performed successfully. The structural properties, energetic heterogeneities and surface functional groups of CG-ACs were characterized using different techniques like nitrogen sorption data, adsorption energy distribution (AED) and X-ray photoelectric spectroscopy (XPS). The electrochemical properties of various CG-ACs were evaluated by using cyclic voltammetry. The maximum specific capacitance value as 257 F g(-1) was obtained in 6 M KOH electrolyte solution. The effects of various properties of the porous carbon materials on the EDLC performance were discussed. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：868 / 871

页数：4

共 20 条

[1] High-capacitance supercapacitor using a nanocomposite electrode of single-walled carbon nanotube and polypyrrole [J].

An, KH ;

Jeon, KK ;

Heo, JK ;

Lim, SC ;

Bae, DJ ;

Lee, YH .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (08) :A1058-A1062

[2] Influence of the solvent properties on the characteristics of a double layer capacitor [J].

Arulepp, M ;

Permann, L ;

Leis, J ;

Perkson, A ;

Rumma, K ;

Jänes, A ;

Lust, E .

JOURNAL OF POWER SOURCES, 2004, 133 (02) :320-328

[3]

BALATHANIGAIMAN.MS, MICROPOR MESOP UNPUB

[4] Chemical and electrochemical characterization of porous carbon materials [J].

Bleda-Martinez, M. J. ;

Lozano-Castello, D. ;

Morallon, E. ;

Cazorla-Amoros, D. ;

Linares-Solano, A. .

CARBON, 2006, 44 (13) :2642-2651

[5] Role of surface chemistry on electric double layer capacitance of carbon materials [J].

Bleda-Martínez, MJ ;

Maciá-Agulló, JA ;

Lozano-Castelló, D ;

Morallón, E ;

Cazorla-Amorós, D ;

Linares-Solano, A .

CARBON, 2005, 43 (13) :2677-2684

[6] R&D considerations for the performance and application of electrochemical capacitors [J].

Burke, Andrew .

ELECTROCHIMICA ACTA, 2007, 53 (03) :1083-1091

[7] Energetic and structural heterogeneity of synthetic microporous carbons [J].

Choma, J ;

Jaroniec, M .

LANGMUIR, 1997, 13 (05) :1026-1030

[8] Morphology and organic EDLC applications of chemically activated AR-resin-based carbons [J].

Endo, M ;

Kim, YJ ;

Ohta, H ;

Ishii, K ;

Inoue, T ;

Hayashi, T ;

Nishimura, Y ;

Maeda, T ;

Dresselhaus, MS .

CARBON, 2002, 40 (14) :2613-2626

[9] A NMR TECHNIQUE FOR THE ANALYSIS OF PORE STRUCTURE - APPLICATION TO MATERIALS WITH WELL-DEFINED PORE STRUCTURE [J].

GALLEGOS, DP ;

MUNN, K ;

SMITH, DM ;

STERMER, DL .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1987, 119 (01) :127-140

[10] Influence of oxygen treatment on electric double-layer capacitance of activated carbon fabrics [J].

Hsieh, CT ;

Teng, H .

CARBON, 2002, 40 (05) :667-674

← 1 2 →