Chiral resolution of some environmental pollutants by capillary electrophoresis

被引:26
作者
Ali, L
Gupta, VK
Aboul-Enein, HY
机构
[1] King Faisal Specialist Hosp & Res Ctr, Pharmaceut Anal Lab, Biol & Med Res Dept, Riyadh 11211, Saudi Arabia
[2] Indian Inst Technol, Dept Chem, Roorkee, Uttar Pradesh, India
[3] Indian Inst Technol, Natl Inst Hydrol, Roorkee, Uttar Pradesh, India
关键词
capillary electrophoresis; chiral environmental pollutant; chiral recognition mechanisms; chiral resolution; optimization; review;
D O I
10.1002/elps.200390175
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The chiral resolution of the environmental pollutants by capillary electrophoresis is reviewed. Various aspects of the chiral resolution such as chiral selectors, optimization of capillary electrophoresis conditions including composition of the background electrolyte (BGE), pH of the BGE, ionic strength of the BGE, structures and types of the chiral selectors, applied voltage, temperature, structures of the chiral pollutants, use of organic modifiers and other parameters are presented. Furthermore, detection, sample treatment, validation of the methods, and the chiral recognition mechanisms, have been discussed.
引用
收藏
页码:1360 / 1374
页数:15
相关论文
共 76 条
[1]  
Aboul-Enein H.Y., 1997, IMPACT STEREOCHEMIST
[2]  
ABOULENEIN HY, 2003, IN PRESS CHIRAL SEPA
[3]  
Amini A, 2001, ELECTROPHORESIS, V22, P3107, DOI 10.1002/1522-2683(200109)22:15<3107::AID-ELPS3107>3.0.CO
[4]  
2-Z
[5]   HIGHLY ENANTIOSELECTIVE CAPILLARY ELECTROPHORETIC SEPARATIONS WITH DILUTE-SOLUTIONS OF THE MACROCYCLIC ANTIBIOTIC RISTOCETIN-A [J].
ARMSTRONG, DW ;
GASPER, MP ;
RUNDLETT, KL .
JOURNAL OF CHROMATOGRAPHY A, 1995, 689 (02) :285-304
[6]  
BEESLEY TE, 1998, CHIRAL CHROMATOGRAPH
[7]   Enantiomer separation of drugs by capillary electromigration techniques [J].
Blaschke, G ;
Chankvetadze, B .
JOURNAL OF CHROMATOGRAPHY A, 2000, 875 (1-2) :3-25
[8]   ENANTIOSELECTIVE DETERMINATION OF CHLORDANE COMPONENTS USING CHIRAL HIGH-RESOLUTION GAS-CHROMATOGRAPHY MASS-SPECTROMETRY WITH APPLICATION TO ENVIRONMENTAL-SAMPLES [J].
BUSER, HR ;
MULLER, MD ;
RAPPE, C .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1992, 26 (08) :1533-1540
[9]   Separation of brompheniramine enantiomers by capillary electrophoresis and study of chiral recognition mechanisms of cyclodextrins using NMR-spectroscopy, UV spectrometry, electrospray ionization mass spectrometry and X-ray crystallography [J].
Chankvetadze, B ;
Burjanadze, N ;
Pintore, G ;
Bergenthal, D ;
Bergander, K ;
Mühlenbrock, C ;
Breitkreuz, J ;
Blaschke, G .
JOURNAL OF CHROMATOGRAPHY A, 2000, 875 (1-2) :471-484
[10]  
Chankvetadze B., 1997, CAPILLARY ELECTROPHO