A synthetic approach to a novel class of fluorine-bearing reversible addition-fragmentation chain transfer (RAFT) agents: F-RAFT

被引：44

作者：

Theis, A

Stenzel, MH

Davis, TP

Coote, ML ^{[1
]}

Barner-Kowollik, C

机构：

[1] Univ New S Wales, Sch Chem Engn & Ind Chem, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia

[2] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2005年 / 58卷 / 06期

关键词：

D O I：

10.1071/CH05069

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A synthetic route is described to a novel class of reversible addition-fragmentation chain transfer ( RAFT) agents bearing a fluorine Z-group. Such F-RAFT agents are theoretically predicted to allow living free radical polymerization of various monomers without affecting the rate of polymerization, and should also facilitate the construction of block copolymers from monomers with disparate reactivity. The class of F-RAFT agents is exemplified by the example of benzyl fluoro dithioformate (BFDF) in styrene free-radical polymerizations and the process is shown to induce living polymerization.

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收藏

页码：437 / 441

页数：5

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