Developments in the metal chemistry of N-confused porphyrin

被引：186

作者：

Harvey, JD ^{[1
]}

Ziegler, CJ ^{[1
]}

机构：

[1] Univ Akron, Buchtel Coll Arts & Sci, Dept Chem, Akron, OH 44325 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2003年 / 247卷 / 1-2期

关键词：

N-confused porphyrin; 2-aza-21; carbaporphyrin; inverted porphyrin; metalloporphyrin;

D O I：

10.1016/j.cct.2003.07.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Since its discovery as a side product in acid catalyzed condensations in 1994, the metal chemistry of N-confused porphyrins has grown exponentially. Due to the location of an external nitrogen on the porphyrin skeleton, different binding modes are being discovered for N-confused porphyrin as compared to tetraphenylporphyrin. In this paper, the metal chemistry of N-confused porphyrin is discussed, reviewing coordination modes and literature on the metal complexes to date. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：1 / 19

页数：19

共 65 条

[1] A new method for the preparation of oxaporphyrins: Reaction of metallo porphyrins with IF [J].

Ali, H ;

vanLier, JE .

TETRAHEDRON LETTERS, 1997, 38 (47) :8173-8176

[2]

[Anonymous], 2000, PORPHYRIN HDB

[3] PORPHYRINS .44. ELECTRONIC STATES OF CO, NI, RH, AND PD COMPLEXES [J].

ANTIPAS, A ;

GOUTERMAN, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (15) :4896-4901

[4] Photophysical characterization of free-base N-confused tetraphenylporphyrins [J].

Belair, JP ;

Ziegler, CJ ;

Rajesh, CS ;

Modarelli, DA .

JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (27) :6445-6451

[5]

Bendix J, 2000, ANGEW CHEM INT EDIT, V39, P4048, DOI 10.1002/1521-3773(20001117)39:22<4048::AID-ANIE4048>3.0.CO

[6]

2-7

[7] Metal oxidation promoted C-H activation in manganese complexes of N-confused porphyrin [J].

Bohle, DS ;

Chen, WC ;

Hung, CH .

INORGANIC CHEMISTRY, 2002, 41 (13) :3334-3336

[8]

Buchler J. W., 1978, PORPHYRINS, V1, P389

[9] Metal complexes with tetrapyrrole ligands .70. Synthesis, characterization, and variable-temperature H-1-NMR investigations of cerium(IV) and zirconium(IV) double-deckers derived from 2,3,7,8,12,13,17,18-octaethyl-5-methylporphyrin [J].

Buchler, JW ;

Heinz, G .

CHEMISCHE BERICHTE, 1996, 129 (02) :201-205

[10] Synthesis and characterization of iron N-confused porphyrins: Structural evidences of agostic interaction [J].

Chen, WC ;

Hung, CH .

INORGANIC CHEMISTRY, 2001, 40 (20) :5070-+

← 1 2 3 4 5 6 7 →