Mutual effects in the chemical properties of the ruthenium metal center and ancillary ligands upon coordination

被引：81

作者：

Toledo, JC ^{[1
]}

Neto, BDSL ^{[1
]}

Franco, DW ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim Sao Carlos, Av Trabalhador Saocarlense 400, BR-13560970 Sao Carlos, SP, Brazil

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 3-4期

基金：

巴西圣保罗研究基金会;

关键词：

ruthenium ammines; nitrosyl; phosphite; sulfite;

D O I：

10.1016/j.ccr.2004.09.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mutual changes induced in both metal center and selected ligands kinetics and thermodynamic properties, as a consequence of the coordination, are discussed in terms of sigma- and pi-bonding. Ruthenium penta and tetraammines are used as models, focusing the attention on phosphines, phosphites, nitrosyl, sulfite and sulfate as ancillary ligands. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：419 / 431

页数：13

共 94 条

[1] THE BASICITY OF PHOSPHINES [J].

ALLMAN, T ;

GOEL, RG .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1982, 60 (06) :716-722

[2] TRANS-INFLUENCE - ITS MEASUREMENT AND SIGNIFICANCE [J].

APPLETON, TG ;

CLARK, HC ;

MANZER, LE .

COORDINATION CHEMISTRY REVIEWS, 1973, 10 (3-4) :335-422

[3] REDUCTION OF COORDINATED NITROSYLS .3. ALTERNATIVE ROUTES TO CHROMIUM(III) DIMERS AND EVIDENCE FOR COORDINATED HYDROXYLAMINE [J].

ARMOR, JN ;

BUCHBIND.M ;

CHENEY, R .

INORGANIC CHEMISTRY, 1974, 13 (12) :2990-2996

[4] Spectroscopic and electrochemical properties of a new nitrosyl-complex of Ru(II):: trans-[Ru(NO){(CH3CH2)2PCH2CH2P(CH2CH3)2}2Cl](PF6)2 [J].

Bagatin, IA ;

Santos, RHD ;

Franco, DW ;

Magalhaes, A ;

Ferreira, AG .

INORGANICA CHIMICA ACTA, 2002, 333 (333) :109-115

[5] The reduction potential of nitric oxide (NO) and its importance to NO biochemistry [J].

Bartberger, MD ;

Liu, W ;

Ford, E ;

Miranda, KM ;

Switzer, C ;

Fukuto, JM ;

Farmer, PJ ;

Wink, DA ;

Houk, KN .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (17) :10958-10963

[6] Water π-donation in trans-tetraammineruthenium(II):: Effect on coordinated-water properties induced by a trans NO ligand [J].

Bezerra, CWB ;

da Silva, SC ;

Gambardella, MTP ;

Santos, RHA ;

Plicas, LMA ;

Tfouni, E ;

Franco, DW .

INORGANIC CHEMISTRY, 1999, 38 (25) :5660-5667

[7] Ruthenium nitrosyl complexes with N-heterocyclic ligands [J].

Borges, SDS ;

Davanzo, CU ;

Castellano, EE ;

Zukerman-Schpector, J ;

Silva, SC ;

Franco, DW .

INORGANIC CHEMISTRY, 1998, 37 (11) :2670-2677

[8]

Bottomley F., 1989, REACTIONS COORDINATE, V2

[9] KINETICS OF ACID + BASES HYDROLYSES OF CHLOROPENTAAMMINERUTHENIUM(3) ION [J].

BROOMHEAD, JA ;

BASOLO, F ;

PEARSON, RG .

INORGANIC CHEMISTRY, 1964, 3 (06) :826-&

[10] DISULFUR BINUCLEAR RUTHENIUM AMMINES [J].

BRULET, CR ;

ISIED, SS ;

TAUBE, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (14) :4758-4759

← 1 2 3 4 5 6 7 8 9 10 →