Synthesis of 2-dimensional inorganic/organic hybrid polymers: Novel meltable layered alkylsiloxanes

被引：15

作者：

Fujii, K

Fujita, T

Iyi, N

Kodama, H

Kitamura, K

Yamagishi, A

机构：

[1] Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan

[2] Univ Tokyo, Grad Sch Sci, Dept Earth & Planetary Sci, Bunkyo Ku, Tokyo 1130033, Japan

来源：

JOURNAL OF MATERIALS SCIENCE LETTERS | 2003年 / 22卷 / 20期

关键词：

D O I：

10.1023/A:1025779918534

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The synthesis of 2-dimensional inorganic/organic hybrid polymers was discussed. It was found that the differential scanning calorimetric (DSC) measurement showed an endothermic peak at 51.3°C for the C18LSiloxane. The analysis showed that layered alkylsiloxanes exhibited typical thermal behavior with melting points.

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页码：1459 / 1461

页数：3

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共 8 条

[1] Aminated phyllosilicates synthesized via a sol-gel process [J].

da Fonseca, MG ;

Silva, CR ;

Airoldi, C .

LANGMUIR, 1999, 15 (15) :5048-5055

[2] Synthesis of an alkylammonium/magnesium phyllosilicate hybrid nanocomposite consisting of a smectite-like layer and organosiloxane layers [J].

Fujii, K ;

Hayashi, S ;

Kodama, H .

CHEMISTRY OF MATERIALS, 2003, 15 (05) :1189-1197

[3] AN ORGANIC/INORGANIC HYBRID LAYERED POLYMER - METHACRYLATE MAGNESIUM (NICKEL) PHYLLOSILICATE [J].

FUKUSHIMA, Y ;

TANI, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (02) :241-242

[4] Polypropylene/Montmorillonite nanocomposites. Review of the synthetic routes and materials properties [J].

Manias, E ;

Touny, A ;

Wu, L ;

Strawhecker, K ;

Lu, B ;

Chung, TC .

CHEMISTRY OF MATERIALS, 2001, 13 (10) :3516-3523

[5] n-alkylsiloxanes: From single monolayers to layered crystals. The formation of crystalline polymers from the hydrolysis of n-octadecyltrichlorosilane [J].

Parikh, AN ;

Schivley, MA ;

Koo, E ;

Seshadri, K ;

Aurentz, D ;

Mueller, K ;

Allara, DL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (13) :3135-3143

[6] Structural control of multilayered inorganic-organic hybrids derived from mixtures of alkyltriethoxysilane and tetraethoxysilane [J].

Shimojima, A ;

Kuroda, K .

LANGMUIR, 2002, 18 (04) :1144-1149

[7] Synthesis of oriented inorganic-organic nanocomposite films from alkyltrialkoxysilane-tetraalkoxysilane mixtures [J].

Shimojima, A ;

Sugahara, Y ;

Kuroda, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (18) :4528-4529

[8] Inorganic-organic layered materials derived via the hydrolysis and polycondensation of trialkoxy(alkyl)silanes [J].

Shimojima, A ;

Sugahara, Y ;

Kuroda, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (11) :2847-2853