Tetrahedral n-type materials:: Efficient quenching of the excitation of p-type polymers in amorphous films

被引:78
作者
Ganesan, P
Yang, XN
Loos, J
Savenije, TJ
Abellon, RD
Zuilhof, H
Sudhölter, EJR
机构
[1] Univ Wageningen & Res Ctr, Organ Chem Lab, NL-6703 HB Wageningen, Netherlands
[2] DPI, NL-5600 AX Eindhoven, Netherlands
[3] Eindhoven Univ Technol, NL-5600 MB Eindhoven, Netherlands
[4] Delft Univ Technol, Optoelect Mat Sect, NL-2629 JB Delft, Netherlands
关键词
D O I
10.1021/ja053689m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tetrahedral naphthalenediimide compound 1 has been synthesized as an example of a new class of amorphous n-type materials, in which the nondirectionality obtained by its shape is decoupled from its optoelectronic properties. 1 forms bicontinuous films with p-type polymers and effectively quenches the excited state, yielding long-lived mobile charge carriers on pulsed illumination. Copyright © 2005 American Chemical Society.
引用
收藏
页码:14530 / 14531
页数:2
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