1,1'-Diphenyl-1,1'-bicyclopropyl and 1,1'-diphenyl-1,1'-bicyclobutyl

被引：6

作者：

Lam, YL

Koh, LL

Huang, HH

机构：

[1] Department of Chemistry, National University of Singapore, Singapore 0511, Lower Kent Ridge Road

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195011929

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecules of 1,1'-diphenyl-1,1'-bicyclopropyl, C18H18, and 1,1'-diphenyl-1,1'-bicyclobutyl, C20H22, each possess a crystallographic centre of symmetry Both molecules adopt the trans conformation. The cyclopropyl rings are approximately symmetric while the cyclobutyl rings are slightly folded.

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页码：397 / 400

页数：4

相关论文

共 16 条

[1] THERMOLABILE HYDROCARBONS .2. RING SIZE EFFECTS ON RATES OF THERMOLYSIS OF 1,1'-DIPHENYL-1,1'-BICYCLOALKYLS [J].

BECKHAUS, HD ;

SCHOCH, J ;

RUCHARDT, C .

CHEMISCHE BERICHTE-RECUEIL, 1976, 109 (04) :1369-1383

[2] THERMOLABILE HYDROCARBONS .25. RELATIONSHIPS BETWEEN THERMAL-STABILITY, STRAIN, AND STRUCTURE OF 1,1'-DIPHENYL-1,1'-BICYCLOALKYLS [J].

BERNLOHR, W ;

BECKHAUS, HD ;

LINDNER, HJ ;

RUCHARDT, C .

CHEMISCHE BERICHTE-RECUEIL, 1984, 117 (11) :3303-3319

[3] THE DEVELOPMENT AND USE OF QUANTUM-MECHANICAL MOLECULAR-MODELS .76. AM1 - A NEW GENERAL-PURPOSE QUANTUM-MECHANICAL MOLECULAR-MODEL [J].

DEWAR, MJS ;

ZOEBISCH, EG ;

HEALY, EF ;

STEWART, JJP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3902-3909

[4] CRYSTAL STRUCTURE OF BICYCLOPROPYL [J].

ERAKER, J ;

ROMMING, C .

ACTA CHEMICA SCANDINAVICA, 1967, 21 (10) :2721-&

[5]

JOHNSON CK, 1965, ORNL3794

[6] STRUCTURE, SYNTHESIS, AND PROPERTIES OF SOME PERSUBSTITUTED 1,2-DINITROETHANES - IN QUEST OF NITROCYCLOPROPYL-ANION DERIVATIVES [J].

KAI, Y ;

KNOCHEL, P ;

KWIATKOWSKI, S ;

DUNITZ, JD ;

OTH, JFM ;

SEEBACH, D ;

KALINOWSKI, HO .

HELVETICA CHIMICA ACTA, 1982, 65 (01) :137-161

[7] STRUCTURES OF 1,1'-DICYANOBICYCLOPENTYL, 1,1'-DICYANOBICYCLOHEXYL AND 1,1'-DICYANOBICYCLOHEPTYL [J].

KOH, LL ;

HUANG, HH ;

SIM, KY .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 :1641-1645

[8] THE CRYSTAL-STRUCTURES OF 1,1'-DINITROBICYCLOPENTYL, 1,1'-DINITROBICYCLOHEXYL AND 1,1'-DINITROBICYCLOHEPTYL [J].

LAM, YL ;

HUANG, HH ;

HAMBLEY, TW .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (12) :2039-2043

[9] SIMPLIFIED METHOD FOR TITANIUM(II)-INDUCED COUPLING OF ALLYLIC AND BENZYLIC ALCOHOLS [J].

MCMURRY, JE ;

SILVESTRI, M .

JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (18) :2687-2688

[10] CONFORMATION AND STRUCTURE OF 1,1'-BICYCLOPROPYL-1,1'-DICARBONITRILE [J].

SCHRUMPF, G ;

JONES, PG .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 :1594-1597