Structure and magnetic properties of a chiral two-dimensional ferrimagnet with Tc of 38 K

被引：200

作者：

Inoue, K ^{[1
]}

Kikuchi, K

Ohba, M

Ökawa, H

机构：

[1] Okazaki Natl Res Inst, Inst Mol Sci, Dept Appl Mol Sci 1, Okazaki, Aichi 4448585, Japan

[2] Tokyo Metropolitan Univ, Dept Chem, Hachioji, Tokyo 1920367, Japan

[3] Kyushu Univ, Grad Sch Sci, Dept Chem, Fukuoka 8128581, Japan

[4] Kyushu Univ, Grad Sch Sci, Dept Chem, Fukuoka 8128581, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 39期

关键词：

chiral resolution; chromium; circular dichroism; magnetic properties; manganese;

D O I：

10.1002/anie.200351888

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Large single crystals of the chiral ferrimagnet [{Cr(CN) 6}{Mn(S)-pnH-(H2O)}](H2O) can be recovered from the reaction between K3[Cr(CN)6], Mn(ClO 4)2, and (S)-1,2-diaminopropane dihydrochloride (see picture). Magnetic measurements of the complex show that MnII and CrIII ions interact ferrimagnetically, with a magnetic transition occurring at 38 K.

引用

页码：4810 / 4813

页数：4

共 19 条

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